Laser ablation synthesis of arsenic phosphides AsmPn clusters from As P mixtures. Laser desorption ionisation with quadrupole ion trap time of flight mass spectrometry. Mass spectrometer as a synthesizer

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F18%3A00102522" target="_blank" >RIV/00216224:14310/18:00102522 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/rcm.8106" target="_blank" >http://dx.doi.org/10.1002/rcm.8106</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/rcm.8106" target="_blank" >10.1002/rcm.8106</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Laser ablation synthesis of arsenic phosphides AsmPn clusters from As P mixtures. Laser desorption ionisation with quadrupole ion trap time of flight mass spectrometry. Mass spectrometer as a synthesizer

Popis výsledku v původním jazyce

Only a few arsenic phosphides are known. High potential for the generation of new compounds is offered by Laser Ablation Synthesis and when Laser Desorption Ionization is coupled with simultaneous Time of Flight Mass Spectrometry, immediate identification of the clusters can be achieved. LAS was used for the generation of arsenic phosphides via laser ablation of phosphorus arsenic mixtures while quadrupole ion trap time of flight mass spectrometry was used to acquire the mass spectra. Many new AsmPn clusters not yet described in the literature were generated in the gas phase and their stoichiometry determined. The likely structures for some of the observed clusters arbitrary selected were computed by DFT optimization. LAS is an advantageous approach for the generation of new AsmPn clusters, while mass spectrometry was found to be an efficient technique for the determination of cluster stoichiometry. The results achieved might inspire the synthesis of new materials.

Název v anglickém jazyce

Laser ablation synthesis of arsenic phosphides AsmPn clusters from As P mixtures. Laser desorption ionisation with quadrupole ion trap time of flight mass spectrometry. Mass spectrometer as a synthesizer

Popis výsledku anglicky

Only a few arsenic phosphides are known. High potential for the generation of new compounds is offered by Laser Ablation Synthesis and when Laser Desorption Ionization is coupled with simultaneous Time of Flight Mass Spectrometry, immediate identification of the clusters can be achieved. LAS was used for the generation of arsenic phosphides via laser ablation of phosphorus arsenic mixtures while quadrupole ion trap time of flight mass spectrometry was used to acquire the mass spectra. Many new AsmPn clusters not yet described in the literature were generated in the gas phase and their stoichiometry determined. The likely structures for some of the observed clusters arbitrary selected were computed by DFT optimization. LAS is an advantageous approach for the generation of new AsmPn clusters, while mass spectrometry was found to be an efficient technique for the determination of cluster stoichiometry. The results achieved might inspire the synthesis of new materials.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

<a href="/cs/project/LO1411" target="_blank" >LO1411: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Rapid Communications in Mass Spectrometry

ISSN

1097-0231

e-ISSN

1097-0231

Svazek periodika

32

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

12

Strana od-do

789-800

Kód UT WoS článku

000430691600004

EID výsledku v databázi Scopus

2-s2.0-85045854139