Redefinition of theresemagnanite, NaCo4(SO4)(OH)(6)C1.6H2O: new data and relationship to 'cobaltogordaite'

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F18%3A00106695" target="_blank" >RIV/00216224:14310/18:00106695 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1180/minmag.2017.081.030" target="_blank" >http://dx.doi.org/10.1180/minmag.2017.081.030</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1180/minmag.2017.081.030" target="_blank" >10.1180/minmag.2017.081.030</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Redefinition of theresemagnanite, NaCo4(SO4)(OH)(6)C1.6H2O: new data and relationship to 'cobaltogordaite'

Popis výsledku v původním jazyce

Theresemagnanite was riginally described frm the Cap Garnne mine, Var, France. Its ideal frmula was reprted as (C,Zn,Ni)(6)(S-4)(H,Cl)(10).8H(2)O; withut crystal structure data, nly the pwder X-ray diffractin pattern was given. Revisin f the hltype material revealed that theresemagnanite is identical t cbaltgrdaite (IMA2014-043), recently described frm the Blue Lizard mine, Utah, USA. Theresemagnanite is thus redefined in accrdance with the new data btained fr the netype specimen frm Blue Lizard (frmerly the hltype specimen f cbaltgrdaite) and cbaltgrdaite has been discredited by the Internatinal Mineralgical Assciatin Cmmissin n New Mineral Nmenclature and Classificatin (IMA CNMNC). Theresemagnanite has the ideal, end-member frmula NaCo4(SO4)(OH)(6)Cl.6H(2)O. The empirical frmulae f the hltype (Cap Garnne) and the netype (Blue Lizard), bth based n micrprbe analyses and calculated n the basis f 17 O | Cl atms per frmula unit (with fixed 6 H grups and 6 H-2 mlecules; H cntent is calculated by stichimetry) are (Na0.64K0.09)Sigma(0.73)(Co2.35Zn1.22Ni0.50)(Sigma 4.07)S1.02O3.98(OH)(6)Cl-1.02.6H(2)O and Na-1.01(Co1.90Zn1.37Ni0.48Cu0.15Mn0.05)(Sigma 3.95)S1.03O4.09(OH)(6)Cl-0.91.6H(2)O, respectively. Theresemagnanite is trignal, P3, a = 8.349(3), c = 13.031(2) angstrom, V = 786.6(4) angstrom 3 and Z = 2 (netype). The strngest pwder X-ray diffractin lines are [d(obs) in angstrom (hkl) (I-rel)]: 13.10 (001)(100), 6.53 (002)(8), 4.173 (110)(4), 3.517 (112)(5), 2.975 (10&lt;(4)ver bar&gt;, 10 )(4), 2.676 (211)(5) and 2.520 (12&lt;(2)ver bar&gt;)(5) (netype). Theresemagnanite is a cbalt analgue f grdaite, NaZn4(SO4)(OH)6Cl.6H(2)O. These minerals represent the grdaite grup, accepted by the IMA CNMNC.

Název v anglickém jazyce

Redefinition of theresemagnanite, NaCo4(SO4)(OH)(6)C1.6H2O: new data and relationship to 'cobaltogordaite'

Popis výsledku anglicky

Theresemagnanite was riginally described frm the Cap Garnne mine, Var, France. Its ideal frmula was reprted as (C,Zn,Ni)(6)(S-4)(H,Cl)(10).8H(2)O; withut crystal structure data, nly the pwder X-ray diffractin pattern was given. Revisin f the hltype material revealed that theresemagnanite is identical t cbaltgrdaite (IMA2014-043), recently described frm the Blue Lizard mine, Utah, USA. Theresemagnanite is thus redefined in accrdance with the new data btained fr the netype specimen frm Blue Lizard (frmerly the hltype specimen f cbaltgrdaite) and cbaltgrdaite has been discredited by the Internatinal Mineralgical Assciatin Cmmissin n New Mineral Nmenclature and Classificatin (IMA CNMNC). Theresemagnanite has the ideal, end-member frmula NaCo4(SO4)(OH)(6)Cl.6H(2)O. The empirical frmulae f the hltype (Cap Garnne) and the netype (Blue Lizard), bth based n micrprbe analyses and calculated n the basis f 17 O | Cl atms per frmula unit (with fixed 6 H grups and 6 H-2 mlecules; H cntent is calculated by stichimetry) are (Na0.64K0.09)Sigma(0.73)(Co2.35Zn1.22Ni0.50)(Sigma 4.07)S1.02O3.98(OH)(6)Cl-1.02.6H(2)O and Na-1.01(Co1.90Zn1.37Ni0.48Cu0.15Mn0.05)(Sigma 3.95)S1.03O4.09(OH)(6)Cl-0.91.6H(2)O, respectively. Theresemagnanite is trignal, P3, a = 8.349(3), c = 13.031(2) angstrom, V = 786.6(4) angstrom 3 and Z = 2 (netype). The strngest pwder X-ray diffractin lines are [d(obs) in angstrom (hkl) (I-rel)]: 13.10 (001)(100), 6.53 (002)(8), 4.173 (110)(4), 3.517 (112)(5), 2.975 (10&lt;(4)ver bar&gt;, 10 )(4), 2.676 (211)(5) and 2.520 (12&lt;(2)ver bar&gt;)(5) (netype). Theresemagnanite is a cbalt analgue f grdaite, NaZn4(SO4)(OH)6Cl.6H(2)O. These minerals represent the grdaite grup, accepted by the IMA CNMNC.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10504 - Mineralogy

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Mineralogical Magazine

ISSN

0026-461X

e-ISSN

—

Svazek periodika

82

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

12

Strana od-do

159-170

Kód UT WoS článku

000435648800011

EID výsledku v databázi Scopus

2-s2.0-85048880851