Secondary beryl in cordierite/sekaninaite pseudomorphs from granitic pegmatites – A monitor of elevated content of beryllium in the precursor

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F20%3A00118576" target="_blank" >RIV/00216224:14310/20:00118576 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216305:26310/20:PU142615

Výsledek na webu

<a href="https://doi.org/10.3749/canmin.2000014" target="_blank" >https://doi.org/10.3749/canmin.2000014</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3749/canmin.2000014" target="_blank" >10.3749/canmin.2000014</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Secondary beryl in cordierite/sekaninaite pseudomorphs from granitic pegmatites – A monitor of elevated content of beryllium in the precursor

Popis výsledku v původním jazyce

Cordierite-group minerals (cordierite and sekaninaite) from granitic pegmatites are often strongly to completely altered to a fine- or coarse-grained mixture of muscovite, chlorite and/or, biotite, along with several less common secondary minerals, including mainly paragonite, tourmaline, and secondary beryl. The mixture is a common product of early subsolidus hydrothermal alteration at the examined pegmatites of the beryl-columbite subtype – Věžná I and Drahonín (Moldanubian Zone, Czech Republic) and Mount Begbie (Shuswap Complex, Canada); of the beryl-columbite-phosphate subtype – Szklary (Góry Sowie Block, Poland); and of miarolitic intragranitic pegmatites – Zimnik (Massif Strzegom-Sobótka, Poland). We studied in detail (EPMA, LA-ICP-MS) relics of primary cordierite/sekaninaite: Věžná I (Crd77–72Sek27–22MnCrd2–1, Be = 0.39–0.25 apfu, Li = 0.06–0.04 apfu), Drahonín (Crd13–9Sek74–71MnCrd17–16, Be = 0.24–0.18 apfu, Li = 0.07–0.05 apfu), Szklary (Crd50–49Sek30–26MnCrd25–21, Be = 0.45–0.41 apfu, Li ≤ 0.02 apfu), Mount Begbie (Crd34–33Sek53–43MnCrd24–14, Be = 0.33–0.29 apfu, Li = 0.26–0.23 apfu), and Zimnik (Crd2–1Sek75–71MnCrd28–23, Be = 0.25–0.15 apfu, Li = 0.18–0.12 apfu). Secondary beryl has a similar Mg/(Mg+Fe) ratio to its cordierite/sekaninaite precursor but is Mn depleted. The mineral assemblages and textures of the pseudomorphs were examined with a focus on secondary beryl, which forms anhedral grains to subhedral elongated crystals, up to 0.3 mm in size, or aggregates of these in textural equilibrium with associated phyllosilicates and tourmaline. Tourmaline is known from Věžná I, Drahonín, Mount Begbie, and Zimnik, the last also with topaz and “zinnwaldite” (a mineral with chemical composition between siderophyllite and polylithionite). Secondary beryl in pseudomorphs after cordierite/sekaninaite from granitic pegmatites and more evolved granites may have been often overlooked; hence, we present its textures and morphology so that it can be recognized during routine EPMA study and to study the source of elevated concentrations of Be in primary cordierite/sekaninaite. The empirical limit of detection of secondary beryl in pseudomorphs is ∼500–1000 ppm Be, which corresponds to ∼1–2 vol.% of secondary beryl. The chemical composition of the secondary beryl and other minerals indicate that the fluids responsible for the alteration were exsolved from the residual pegmatite melt and were not contaminated by fluids from the host rocks.

Název v anglickém jazyce

Secondary beryl in cordierite/sekaninaite pseudomorphs from granitic pegmatites – A monitor of elevated content of beryllium in the precursor

Popis výsledku anglicky

Cordierite-group minerals (cordierite and sekaninaite) from granitic pegmatites are often strongly to completely altered to a fine- or coarse-grained mixture of muscovite, chlorite and/or, biotite, along with several less common secondary minerals, including mainly paragonite, tourmaline, and secondary beryl. The mixture is a common product of early subsolidus hydrothermal alteration at the examined pegmatites of the beryl-columbite subtype – Věžná I and Drahonín (Moldanubian Zone, Czech Republic) and Mount Begbie (Shuswap Complex, Canada); of the beryl-columbite-phosphate subtype – Szklary (Góry Sowie Block, Poland); and of miarolitic intragranitic pegmatites – Zimnik (Massif Strzegom-Sobótka, Poland). We studied in detail (EPMA, LA-ICP-MS) relics of primary cordierite/sekaninaite: Věžná I (Crd77–72Sek27–22MnCrd2–1, Be = 0.39–0.25 apfu, Li = 0.06–0.04 apfu), Drahonín (Crd13–9Sek74–71MnCrd17–16, Be = 0.24–0.18 apfu, Li = 0.07–0.05 apfu), Szklary (Crd50–49Sek30–26MnCrd25–21, Be = 0.45–0.41 apfu, Li ≤ 0.02 apfu), Mount Begbie (Crd34–33Sek53–43MnCrd24–14, Be = 0.33–0.29 apfu, Li = 0.26–0.23 apfu), and Zimnik (Crd2–1Sek75–71MnCrd28–23, Be = 0.25–0.15 apfu, Li = 0.18–0.12 apfu). Secondary beryl has a similar Mg/(Mg+Fe) ratio to its cordierite/sekaninaite precursor but is Mn depleted. The mineral assemblages and textures of the pseudomorphs were examined with a focus on secondary beryl, which forms anhedral grains to subhedral elongated crystals, up to 0.3 mm in size, or aggregates of these in textural equilibrium with associated phyllosilicates and tourmaline. Tourmaline is known from Věžná I, Drahonín, Mount Begbie, and Zimnik, the last also with topaz and “zinnwaldite” (a mineral with chemical composition between siderophyllite and polylithionite). Secondary beryl in pseudomorphs after cordierite/sekaninaite from granitic pegmatites and more evolved granites may have been often overlooked; hence, we present its textures and morphology so that it can be recognized during routine EPMA study and to study the source of elevated concentrations of Be in primary cordierite/sekaninaite. The empirical limit of detection of secondary beryl in pseudomorphs is ∼500–1000 ppm Be, which corresponds to ∼1–2 vol.% of secondary beryl. The chemical composition of the secondary beryl and other minerals indicate that the fluids responsible for the alteration were exsolved from the residual pegmatite melt and were not contaminated by fluids from the host rocks.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10504 - Mineralogy

Projekt

<a href="/cs/project/GA17-17276S" target="_blank" >GA17-17276S: Turmalín - indikátor geologických procesů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Canadian Mineralogist

ISSN

0008-4476

e-ISSN

1499-1276

Svazek periodika

58

Číslo periodika v rámci svazku

6

Stát vydavatele periodika

CA - Kanada

Počet stran výsledku

18

Strana od-do

785-802

Kód UT WoS článku

000637945400008

EID výsledku v databázi Scopus

2-s2.0-85104959168