Elimination voltammetry as an innovative tool of electroanalysis

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F22%3A00125205" target="_blank" >RIV/00216224:14310/22:00125205 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S1572665721009887" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1572665721009887</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jelechem.2021.115961" target="_blank" >10.1016/j.jelechem.2021.115961</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Elimination voltammetry as an innovative tool of electroanalysis

Popis výsledku v původním jazyce

The review presents the application potential of elimination voltammetry with linear scan (EVLS) in the electroanalysis of organic and inorganic electroactive substances. This innovative method can be considered a software tool that transforms the total current-voltage records measured at different scan rates into elimination functions providing new useful information about a given electrode process. Some EVLS functions are capable of separating overlapped voltammetric signals, identifying the adsorbed state of the analyze, and detecting the preceding chemical reaction before the electron transfer. EVLS finds use in solving the mechanisms of electrode processes and determining significant physicochemical parameters, such as charge transfer coefficients and electrochemical equilibrium protonation constants. This review selects and draws attention to certain problems that may accompany EVLS in voltammetric experiments on solid electrodes.

Název v anglickém jazyce

Elimination voltammetry as an innovative tool of electroanalysis

Popis výsledku anglicky

The review presents the application potential of elimination voltammetry with linear scan (EVLS) in the electroanalysis of organic and inorganic electroactive substances. This innovative method can be considered a software tool that transforms the total current-voltage records measured at different scan rates into elimination functions providing new useful information about a given electrode process. Some EVLS functions are capable of separating overlapped voltammetric signals, identifying the adsorbed state of the analyze, and detecting the preceding chemical reaction before the electron transfer. EVLS finds use in solving the mechanisms of electrode processes and determining significant physicochemical parameters, such as charge transfer coefficients and electrochemical equilibrium protonation constants. This review selects and draws attention to certain problems that may accompany EVLS in voltammetric experiments on solid electrodes.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Electroanalytical Chemistry

ISSN

1572-6657

e-ISSN

—

Svazek periodika

905

Číslo periodika v rámci svazku

January

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

9

Strana od-do

115961

Kód UT WoS článku

000741300200008

EID výsledku v databázi Scopus

2-s2.0-85122008249