HARRISONITE, A RARE SILICATE-PHOSPHATE FROM GRANITIC PEGMATITES OF THE BOHEMIAN MASSIF

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F22%3A00125826" target="_blank" >RIV/00216224:14310/22:00125826 - isvavai.cz</a>

Výsledek na webu

<a href="http://scigeo.actamm.cz/en/harrisonite-a-rare-silicate-phosphate-from-granitic-pegmatites-of-the-bohemian-massif/" target="_blank" >http://scigeo.actamm.cz/en/harrisonite-a-rare-silicate-phosphate-from-granitic-pegmatites-of-the-bohemian-massif/</a>

DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

HARRISONITE, A RARE SILICATE-PHOSPHATE FROM GRANITIC PEGMATITES OF THE BOHEMIAN MASSIF

Popis výsledku v původním jazyce

Harrisonite, CaFe2+6(SiO4)2(PO4)2, is a rare silicate-phosphate described as a rock-forming mineral from highly metamorphosed garnetites (originally BIF) from Canada. Disregarding several questionable anthro pogenic occurrences of harrisonite, the mineral has also been scarcely found in the phosphatebearing granitic pegmatites Cyrilov (Czech Republic), Jocão (Brazil) and Přibyslavice (Czech Republic). The ori ginal harrisonite from garnetites is Mg-rich and Mn-poor, while that from pegmatites is enriched in Mn and poor in Mg. The average empirical formulae of harrisonite from Cyrilov and Přibyslavice based on 16 O are very similar, and are as follows: Ca0.98(Fe5.37Mn0.33Mg0.05Zn0.01)Σ5.76Si1.87P2.20O16, and Ca0.98(Fe5.37Mn0.33Mg0.06)Σ5.76Si1.89P2.19O16, respectively. Tetrahedrally coordinated Si in harrisonite from Přibyslavice and Cyrilov is often deficient and compensated by surplus of P. This surplus of P negatively correlates with the divalent cation contents, particularly Fe2+, which might indicate a participation of the MO6 polyhedron vacancies as a charge-balancing mechanism. The presence of harrisonite in phosphate-bearing granitic pegmatites is pointing out that the mineral is stable even at lower P–T conditions than reported from the type occurrence.

Název v anglickém jazyce

HARRISONITE, A RARE SILICATE-PHOSPHATE FROM GRANITIC PEGMATITES OF THE BOHEMIAN MASSIF

Popis výsledku anglicky

Harrisonite, CaFe2+6(SiO4)2(PO4)2, is a rare silicate-phosphate described as a rock-forming mineral from highly metamorphosed garnetites (originally BIF) from Canada. Disregarding several questionable anthro pogenic occurrences of harrisonite, the mineral has also been scarcely found in the phosphatebearing granitic pegmatites Cyrilov (Czech Republic), Jocão (Brazil) and Přibyslavice (Czech Republic). The ori ginal harrisonite from garnetites is Mg-rich and Mn-poor, while that from pegmatites is enriched in Mn and poor in Mg. The average empirical formulae of harrisonite from Cyrilov and Přibyslavice based on 16 O are very similar, and are as follows: Ca0.98(Fe5.37Mn0.33Mg0.05Zn0.01)Σ5.76Si1.87P2.20O16, and Ca0.98(Fe5.37Mn0.33Mg0.06)Σ5.76Si1.89P2.19O16, respectively. Tetrahedrally coordinated Si in harrisonite from Přibyslavice and Cyrilov is often deficient and compensated by surplus of P. This surplus of P negatively correlates with the divalent cation contents, particularly Fe2+, which might indicate a participation of the MO6 polyhedron vacancies as a charge-balancing mechanism. The presence of harrisonite in phosphate-bearing granitic pegmatites is pointing out that the mineral is stable even at lower P–T conditions than reported from the type occurrence.

Druh

J_SC - Článek v periodiku v databázi SCOPUS

CEP obor

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OECD FORD obor

10504 - Mineralogy

Projekt

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Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Acta Mus. Moraviae, Sci. geol.

ISSN

1211-8796

e-ISSN

2571-4686

Svazek periodika

107

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

CZ - Česká republika

Počet stran výsledku

12

Strana od-do

21-32

Kód UT WoS článku

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EID výsledku v databázi Scopus

2-s2.0-85130838499