Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F25%3A00142065" target="_blank" >RIV/00216224:14310/25:00142065 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.acs.org/doi/10.1021/acsestwater.5c00384" target="_blank" >https://pubs.acs.org/doi/10.1021/acsestwater.5c00384</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsestwater.5c00384" target="_blank" >10.1021/acsestwater.5c00384</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters

Popis výsledku v původním jazyce

Passive sampling in surface waters is an important method in the monitoring and risk assessment of hydrophobic and hydrophilic organic chemicals. Sampler designs can be optimized for fast equilibrium attainment (equilibrium sampling) or improved time-integrative capability (kinetic sampling). We argue that both equilibrium and kinetic sampling can be applied when aqueous concentrations do not vary with time, whereas kinetic sampling also yields useful results for time-variable concentrations that are often observed with hydrophilic compounds in surface waters. We show that these methods have similar accuracy in principle but that their dominant error sources are different: sampler-water sorption coefficients for equilibrium sampling and sampling rates for kinetic sampling. In contrast to passive sampling of hydrophobic compounds, passive sampling of hydrophilic compounds is not as well-established, but major progress has been made over the past decade in the modeling of transport through the water boundary layer, membrane, and sorbent, while less progress has been made for transport in the biofouling layer. We recommend a more extensive use of diffusion cells as a research tool to gain a better understanding of transport through the respective subphases, leading to a greater maturity of passive water sampling of hydrophilic compounds.

Název v anglickém jazyce

Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters

Popis výsledku anglicky

Passive sampling in surface waters is an important method in the monitoring and risk assessment of hydrophobic and hydrophilic organic chemicals. Sampler designs can be optimized for fast equilibrium attainment (equilibrium sampling) or improved time-integrative capability (kinetic sampling). We argue that both equilibrium and kinetic sampling can be applied when aqueous concentrations do not vary with time, whereas kinetic sampling also yields useful results for time-variable concentrations that are often observed with hydrophilic compounds in surface waters. We show that these methods have similar accuracy in principle but that their dominant error sources are different: sampler-water sorption coefficients for equilibrium sampling and sampling rates for kinetic sampling. In contrast to passive sampling of hydrophobic compounds, passive sampling of hydrophilic compounds is not as well-established, but major progress has been made over the past decade in the modeling of transport through the water boundary layer, membrane, and sorbent, while less progress has been made for transport in the biofouling layer. We recommend a more extensive use of diffusion cells as a research tool to gain a better understanding of transport through the respective subphases, leading to a greater maturity of passive water sampling of hydrophilic compounds.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10503 - Water resources

Projekt

<a href="/cs/project/GX20-04676X" target="_blank" >GX20-04676X: Holistická charakterizace expozice a potenciálních účinků komplexních směsí chemických látek ve vodním prostředí</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS ES&amp;T WATER

ISSN

2690-0637

e-ISSN

2690-0637

Svazek periodika

5

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

4343-4350

Kód UT WoS článku

001535132400001

EID výsledku v databázi Scopus

2-s2.0-105014650678