Inclusion compounds of cystostatic active (C5H5)2 VCl2 and (CH3C5H4)2 VCl2 with a-, b- and c- cyclodextrines: Synthesis, EPR study and microbiological behavior toward Escherichia coli.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F05%3A00001636" target="_blank" >RIV/00216275:25310/05:00001636 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Inclusion compounds of cystostatic active (C5H5)2 VCl2 and (CH3C5H4)2 VCl2 with a-, b- and c- cyclodextrines: Synthesis, EPR study and microbiological behavior toward Escherichia coli.

Popis výsledku v původním jazyce

The inclusion of vanadocene dichloride (VDC) and 1,1'-dimethyl vanadocene dichloride (MeVDC) into cyclodextrines (a-CD, b-CD and c-CD) was studied by EPR spectroscopy. It was found that VDC and MeVDC with b-CD and c-CD form true inclusion compounds, butwith a-CD, VDC and MeVDC gave only fine dispersion mixtures. The inclusion was validated by anisotropic EPR spectra of solid samples. In addition, the antimicrobial behavior (against E. coli) of each of the complexes was determined. It was established that not only did VDC and MeVDC cause elongation of E. coli, but also the new vanadocene inclusion complexes were effective in this regard.

Název v anglickém jazyce

Inclusion compounds of cystostatic active (C5H5)2 VCl2 and (CH3C5H4)2 VCl2 with a-, b- and c- cyclodextrines: Synthesis, EPR study and microbiological behavior toward Escherichia coli.

Popis výsledku anglicky

The inclusion of vanadocene dichloride (VDC) and 1,1'-dimethyl vanadocene dichloride (MeVDC) into cyclodextrines (a-CD, b-CD and c-CD) was studied by EPR spectroscopy. It was found that VDC and MeVDC with b-CD and c-CD form true inclusion compounds, butwith a-CD, VDC and MeVDC gave only fine dispersion mixtures. The inclusion was validated by anisotropic EPR spectra of solid samples. In addition, the antimicrobial behavior (against E. coli) of each of the complexes was determined. It was established that not only did VDC and MeVDC cause elongation of E. coli, but also the new vanadocene inclusion complexes were effective in this regard.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2005

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Central European Journal of Chemistry

ISSN

1644-3624

e-ISSN

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Svazek periodika

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Číslo periodika v rámci svazku

1

Stát vydavatele periodika

PL - Polská republika

Počet stran výsledku

10

Strana od-do

72-81

Kód UT WoS článku

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EID výsledku v databázi Scopus

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