C, N and N, C, N-chelated Organotin (IV) Fluorides

Kód výsledku v IS VaVaI

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Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

C, N and N, C, N-chelated Organotin (IV) Fluorides

Popis výsledku v původním jazyce

One of the goals in the chemistry of tri-, di-, and monoorganotin(IV) compounds is to prepare and characterize structurally monomeric organotin fluorides, which are of great interest due to their ability to undergo the metathetical halide for fluoride exchange reactions with different kinds of organic, inorganic or organometallic halides. For these purposes, organotin systems containing C,N-chelating or N,C,N-chelating ligands were selected. During the last five years, a set of compounds was prepared and structurally characterized. C,N-chelated triorganotin compounds bearing the LCN ligand, where LCN is {2-[(CH3)2NCH2]C6H4}- , reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom and the longest Sn-F distances due to the trans effect of the lone electron pair of nitrogen. Di-, and monoorganotin(IV) fluorides having either the monomeric and oligomeric structure with hexacoordinated tin atoms and both terminal and bridging fluorine atoms.

Název v anglickém jazyce

C, N and N, C, N-chelated Organotin (IV) Fluorides

Popis výsledku anglicky

One of the goals in the chemistry of tri-, di-, and monoorganotin(IV) compounds is to prepare and characterize structurally monomeric organotin fluorides, which are of great interest due to their ability to undergo the metathetical halide for fluoride exchange reactions with different kinds of organic, inorganic or organometallic halides. For these purposes, organotin systems containing C,N-chelating or N,C,N-chelating ligands were selected. During the last five years, a set of compounds was prepared and structurally characterized. C,N-chelated triorganotin compounds bearing the LCN ligand, where LCN is {2-[(CH3)2NCH2]C6H4}- , reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom and the longest Sn-F distances due to the trans effect of the lone electron pair of nitrogen. Di-, and monoorganotin(IV) fluorides having either the monomeric and oligomeric structure with hexacoordinated tin atoms and both terminal and bridging fluorine atoms.

Druh

C - Kapitola v odborné knize

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2007

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název knihy nebo sborníku

Fluorine Chemistry Research Advances

ISBN

1-60021-730-3

Počet stran výsledku

31

Strana od-do

281-312

Počet stran knihy

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Název nakladatele

Nova Science Publishers

Místo vydání

NY, USA

Kód UT WoS kapitoly

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