Vliv prostředí a mletí na mechanismus krystalizace ZrO2 gelu

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F07%3A00006559" target="_blank" >RIV/00216275:25310/07:00006559 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Influence of Environment and Grinding on the Crystallization Mechanism of ZrO2 Gel

Popis výsledku v původním jazyce

The influence of grinding and surrounding atmosphere on the thermal transformations of zirconia gel has been studied. The XRD analysis of the products obtained by thermal decomposition of zirconia gel has shown that pure tetragonal phase is obtained if the gel decomposition is carried out under high vacuum or dry inert atmosphere, while monoclinic zirconia results from the decomposition of the zirconia gel under air or inert gas saturated with water vapour. A mechanism for the thermal crystallisation ofzirconia gel has been proposed from the study of the variation of the crystal size of the monoclinic and tetragonal zirconia phases formed as a function of the temperature and the surrounding atmosphere. The thermal decomposition of ground zirconia leads to the formation of ZrO2 with a percentage of tetragonal phase closed to 90% irrespectively of the surrounding atmosphere. The stabilisation of the tetragonal phase by grinding seems to be connected with the formation of tetragonal zirc

Název v anglickém jazyce

Influence of Environment and Grinding on the Crystallization Mechanism of ZrO2 Gel

Popis výsledku anglicky

The influence of grinding and surrounding atmosphere on the thermal transformations of zirconia gel has been studied. The XRD analysis of the products obtained by thermal decomposition of zirconia gel has shown that pure tetragonal phase is obtained if the gel decomposition is carried out under high vacuum or dry inert atmosphere, while monoclinic zirconia results from the decomposition of the zirconia gel under air or inert gas saturated with water vapour. A mechanism for the thermal crystallisation ofzirconia gel has been proposed from the study of the variation of the crystal size of the monoclinic and tetragonal zirconia phases formed as a function of the temperature and the surrounding atmosphere. The thermal decomposition of ground zirconia leads to the formation of ZrO2 with a percentage of tetragonal phase closed to 90% irrespectively of the surrounding atmosphere. The stabilisation of the tetragonal phase by grinding seems to be connected with the formation of tetragonal zirc

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2007

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Physics and Chemistry of Solids

ISSN

0022-3697

e-ISSN

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Svazek periodika

68

Číslo periodika v rámci svazku

N

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

6

Strana od-do

824-829

Kód UT WoS článku

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EID výsledku v databázi Scopus

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