Study of Reactivity of 4-Halogenoanilines with Metals and Metallic Alloys in Alkaline Aqueous Solution at Room Temperature

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008645" target="_blank" >RIV/00216275:25310/09:00008645 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Study of Reactivity of 4-Halogenoanilines with Metals and Metallic Alloys in Alkaline Aqueous Solution at Room Temperature

Popis výsledku v původním jazyce

This article describes a new simple method for dehalogenation of 4-halogenoanilines in buffered aqueous solution using a reduction technique based on the treatment with the metallic alloy in alkaline conditions at room temperature. Al and Zn metals and Al-Fe, Al-Ni, Cu-Sn, Cu-Zn and Al-Cu-Zn metallic alloys were tested as the reductants. The GC-MS and 1H NMR spectroscopy were used for analyzing the reaction mixtures, and aniline was detected as the single product of the reduction of mentioned 4-halogenoanilines. It was observed that the addition of the metal chelating agent is essentioal for the complete dehalogenation of halogenated anilines in buffered solutions. The possibility of lowering of aniline and Ni2+ content in the aqueous solution was tested using flocculation and extraction

Název v anglickém jazyce

Study of Reactivity of 4-Halogenoanilines with Metals and Metallic Alloys in Alkaline Aqueous Solution at Room Temperature

Popis výsledku anglicky

This article describes a new simple method for dehalogenation of 4-halogenoanilines in buffered aqueous solution using a reduction technique based on the treatment with the metallic alloy in alkaline conditions at room temperature. Al and Zn metals and Al-Fe, Al-Ni, Cu-Sn, Cu-Zn and Al-Cu-Zn metallic alloys were tested as the reductants. The GC-MS and 1H NMR spectroscopy were used for analyzing the reaction mixtures, and aniline was detected as the single product of the reduction of mentioned 4-halogenoanilines. It was observed that the addition of the metal chelating agent is essentioal for the complete dehalogenation of halogenated anilines in buffered solutions. The possibility of lowering of aniline and Ni2+ content in the aqueous solution was tested using flocculation and extraction

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CI - Průmyslová chemie a chemické inženýrství

OECD FORD obor

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Projekt

<a href="/cs/project/GP203%2F07%2FP248" target="_blank" >GP203/07/P248: Čištění kontaminovaných vod redukcí s použitím bimetalických slitin a huminových kyselin</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2009

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Scientific Papers of the University of Pardubice, Series A

ISSN

1211-5541

e-ISSN

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Svazek periodika

2009

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

CZ - Česká republika

Počet stran výsledku

8

Strana od-do

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Kód UT WoS článku

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EID výsledku v databázi Scopus

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