Study of TATP: Influence of reaction conditions on product composition

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F10%3A39882549" target="_blank" >RIV/00216275:25310/10:39882549 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Study of TATP: Influence of reaction conditions on product composition

Popis výsledku v původním jazyce

The influence of reaction conditions (temperature, catalyst type, catalyst concentration - represented as molar ratio catalyst/acetone nc/na) on the composition of the product formed from the reaction of acetone and hydrogen peroxide (30%) under acid catalysis was studied. 3,3,6,6,9,9-Hexamethyl-1,2,4,5,7,8-hexoxonane (TATP) was found to be the major product when the content of the catalyst in the reaction mixture is low (nc/na ? 0.5). A single side product (peak 10.2) in an amount ranging from 1.5 to 8% of the total peak area was present in all the prepared samples. Three other side products were found when catalyzing by hydrochloric and nitric acids. Temperature and catalyst type did not have a significant influence on the composition of the productat low catalyst concentration. Increasing the catalyst concentration led to the formation of 3,3,6,6-tetramethyl-1,2,4,5-tetroxane (DADP) either as a co-product of TATP or as an exclusive product depending on the concentration of the cata

Název v anglickém jazyce

Study of TATP: Influence of reaction conditions on product composition

Popis výsledku anglicky

The influence of reaction conditions (temperature, catalyst type, catalyst concentration - represented as molar ratio catalyst/acetone nc/na) on the composition of the product formed from the reaction of acetone and hydrogen peroxide (30%) under acid catalysis was studied. 3,3,6,6,9,9-Hexamethyl-1,2,4,5,7,8-hexoxonane (TATP) was found to be the major product when the content of the catalyst in the reaction mixture is low (nc/na ? 0.5). A single side product (peak 10.2) in an amount ranging from 1.5 to 8% of the total peak area was present in all the prepared samples. Three other side products were found when catalyzing by hydrochloric and nitric acids. Temperature and catalyst type did not have a significant influence on the composition of the productat low catalyst concentration. Increasing the catalyst concentration led to the formation of 3,3,6,6-tetramethyl-1,2,4,5-tetroxane (DADP) either as a co-product of TATP or as an exclusive product depending on the concentration of the cata

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

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Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Propellants Explosives Pyrotechnics

ISSN

0721-3115

e-ISSN

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Svazek periodika

35

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

7

Strana od-do

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Kód UT WoS článku

000275260200005

EID výsledku v databázi Scopus

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