2D-supramolecular layers built of antiferromagnetically coupled [Cu(x-O(2)Nbz)(2)(denia)(1)(H(2)O)(1)](n) 1D-polymers with R(2)(2)(10) and R(2)(2)(12) supramolecular synthons
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892429" target="_blank" >RIV/00216275:25310/11:39892429 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.poly.2010.09.034" target="_blank" >http://dx.doi.org/10.1016/j.poly.2010.09.034</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2010.09.034" target="_blank" >10.1016/j.poly.2010.09.034</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
2D-supramolecular layers built of antiferromagnetically coupled [Cu(x-O(2)Nbz)(2)(denia)(1)(H(2)O)(1)](n) 1D-polymers with R(2)(2)(10) and R(2)(2)(12) supramolecular synthons
Popis výsledku v původním jazyce
Polymeric complexes of composition [Cu(3.5-(O(2)N)(2)bz)(2)(mu-denia)(1)(H(2)O)(1)](n) (1) (3,5-(O(2)N)(2)bz = 3,5-dinitrobenzoate) and [(Cux-O(2)Nbz)(2)(mu-denia)(1)(H(2)O)(1)] x = 3 (2), x = 4 (3) (denia = diethylnicotinamide, and x-O(2)Nbz = 3- or 4-nitrobenzoate) have been prepared, characterized by elemental analysis and studied by electronic, infrared and EPR spectra, as well as by magnetization measurements over the temperature range 1.8-300 K, and their structures have been solved. The basic structure unit of all complexes consists of Cu(II) atom monodentately coordinated by the pair of nitrobenzoato anions in trans-positions together with water and diethylnicotinamide molecules, forming nearly tetragonal basal plane of the coordination polyhedron. The axial position of tetragonal-pyramidal coordination polyhedron is occupied by diethylnicotinamide oxygen atom of neighbouring structural unit thus forming spiral polymeric molecule parallel to b-axis. The neighbouring polymeric m
Název v anglickém jazyce
2D-supramolecular layers built of antiferromagnetically coupled [Cu(x-O(2)Nbz)(2)(denia)(1)(H(2)O)(1)](n) 1D-polymers with R(2)(2)(10) and R(2)(2)(12) supramolecular synthons
Popis výsledku anglicky
Polymeric complexes of composition [Cu(3.5-(O(2)N)(2)bz)(2)(mu-denia)(1)(H(2)O)(1)](n) (1) (3,5-(O(2)N)(2)bz = 3,5-dinitrobenzoate) and [(Cux-O(2)Nbz)(2)(mu-denia)(1)(H(2)O)(1)] x = 3 (2), x = 4 (3) (denia = diethylnicotinamide, and x-O(2)Nbz = 3- or 4-nitrobenzoate) have been prepared, characterized by elemental analysis and studied by electronic, infrared and EPR spectra, as well as by magnetization measurements over the temperature range 1.8-300 K, and their structures have been solved. The basic structure unit of all complexes consists of Cu(II) atom monodentately coordinated by the pair of nitrobenzoato anions in trans-positions together with water and diethylnicotinamide molecules, forming nearly tetragonal basal plane of the coordination polyhedron. The axial position of tetragonal-pyramidal coordination polyhedron is occupied by diethylnicotinamide oxygen atom of neighbouring structural unit thus forming spiral polymeric molecule parallel to b-axis. The neighbouring polymeric m
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CA - Anorganická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
Z - Vyzkumny zamer (s odkazem do CEZ)
Ostatní
Rok uplatnění
2011
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Polyhedron
ISSN
0277-5387
e-ISSN
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Svazek periodika
30
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
7
Strana od-do
86-92
Kód UT WoS článku
000287059400013
EID výsledku v databázi Scopus
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