A New Solvated Phosphoric Triamide, [(C6H4(3-CH3)NH)(3)P(O)] center dot (C2H5OH): A Database Analysis of N Atom Geometry in Compounds with an [N](3)P(O) Fragment

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896305" target="_blank" >RIV/00216275:25310/13:39896305 - isvavai.cz</a>

Výsledek na webu

<a href="http://www.tandfonline.com/doi/abs/10.1080/10426507.2012.744015#.UrL_VbTtAg5" target="_blank" >http://www.tandfonline.com/doi/abs/10.1080/10426507.2012.744015#.UrL_VbTtAg5</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/10426507.2012.744015" target="_blank" >10.1080/10426507.2012.744015</a>

Jazyk výsledku

angličtina

Název v původním jazyce

A New Solvated Phosphoric Triamide, [(C6H4(3-CH3)NH)(3)P(O)] center dot (C2H5OH): A Database Analysis of N Atom Geometry in Compounds with an [N](3)P(O) Fragment

Popis výsledku v původním jazyce

In the crystal structure of the title compound C21H24N3OP {bold}{/bold} C2H5OH, there are three crystallographically independent phosphoric triamide molecules and three ethanol molecules. The environments of the nitrogen atoms are practically planar. Thephosphorus atoms display a distorted tetrahedral environment; the maximum and minimum values of angles are observed for one OPN and one NPN angles, respectively. In this structure, the phosphoramide and ethanol molecules are linked by some different intermolecular OH{bold}{/bold}O and NH{bold}{/bold}O hydrogen bonds to form chains. The title solvated compound has been further characterized by IR and P-31{H-1}, H-1 and C-13 NMR spectroscopy. The geometry of the nitrogen atoms in this compound is analyzed and compared with those of analogous structures deposited in the Cambridge Structural Database (CSD; Allen, Acta Cryst. 2002, B58, 380-388).

Název v anglickém jazyce

A New Solvated Phosphoric Triamide, [(C6H4(3-CH3)NH)(3)P(O)] center dot (C2H5OH): A Database Analysis of N Atom Geometry in Compounds with an [N](3)P(O) Fragment

Popis výsledku anglicky

In the crystal structure of the title compound C21H24N3OP {bold}{/bold} C2H5OH, there are three crystallographically independent phosphoric triamide molecules and three ethanol molecules. The environments of the nitrogen atoms are practically planar. Thephosphorus atoms display a distorted tetrahedral environment; the maximum and minimum values of angles are observed for one OPN and one NPN angles, respectively. In this structure, the phosphoramide and ethanol molecules are linked by some different intermolecular OH{bold}{/bold}O and NH{bold}{/bold}O hydrogen bonds to form chains. The title solvated compound has been further characterized by IR and P-31{H-1}, H-1 and C-13 NMR spectroscopy. The geometry of the nitrogen atoms in this compound is analyzed and compared with those of analogous structures deposited in the Cambridge Structural Database (CSD; Allen, Acta Cryst. 2002, B58, 380-388).

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Phosphorus Sulfur and Silicon and the Related Elements

ISSN

1042-6507

e-ISSN

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Svazek periodika

188

Číslo periodika v rámci svazku

1-3

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

224-231

Kód UT WoS článku

000319042300057

EID výsledku v databázi Scopus

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