New thiocyanato iron(II) complex with 3,5-bis(3-pyridyl)-1,2,4-thiadiazole: Synthesis, structure, magnetic and spectral properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898444" target="_blank" >RIV/00216275:25310/14:39898444 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.ica.2014.01.032" target="_blank" >http://dx.doi.org/10.1016/j.ica.2014.01.032</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ica.2014.01.032" target="_blank" >10.1016/j.ica.2014.01.032</a>

Jazyk výsledku

angličtina

Název v původním jazyce

New thiocyanato iron(II) complex with 3,5-bis(3-pyridyl)-1,2,4-thiadiazole: Synthesis, structure, magnetic and spectral properties

Popis výsledku v původním jazyce

The new iron(II) complex [Fe(NCS)(2)(CH3OH)(2)(bpta)(2)] (bpta = 3,5-bis(3-pyridyl)-1,2,4-thiadiazole) has been prepared by refluxing Fe(NCS)(3) or Fe(NCS)(2) with thionicotinamide in methanol solution. It is supposed that the bpta ligand is generated insitu by the oxidative dimerization of thionicotinamide. The complex was characterized by X-ray structural analysis at 150 and 293 K, elemental analysis, spectral and magnetic measurements. The compound crystallizes in the monoclinic P2(1) space group, with unit cell parameters at 293 K: a = 7.869(2), b = 17.056(3), c = 12.637(3) angstrom, beta = 102.88(1)degrees. The crystal structure analysis showed that the iron atom has a distorted octahedral environment with FeN4O2 chromophore. Iron atom is coordinated by two nitrogen atoms from NCS ions, by two oxygen atoms from methanol molecules in the equatorial plane and by two nitrogen atoms of pyridine rings from dpta ligands in axial positions. The crystal lattice forms 2D supramolecular ne

Název v anglickém jazyce

New thiocyanato iron(II) complex with 3,5-bis(3-pyridyl)-1,2,4-thiadiazole: Synthesis, structure, magnetic and spectral properties

Popis výsledku anglicky

The new iron(II) complex [Fe(NCS)(2)(CH3OH)(2)(bpta)(2)] (bpta = 3,5-bis(3-pyridyl)-1,2,4-thiadiazole) has been prepared by refluxing Fe(NCS)(3) or Fe(NCS)(2) with thionicotinamide in methanol solution. It is supposed that the bpta ligand is generated insitu by the oxidative dimerization of thionicotinamide. The complex was characterized by X-ray structural analysis at 150 and 293 K, elemental analysis, spectral and magnetic measurements. The compound crystallizes in the monoclinic P2(1) space group, with unit cell parameters at 293 K: a = 7.869(2), b = 17.056(3), c = 12.637(3) angstrom, beta = 102.88(1)degrees. The crystal structure analysis showed that the iron atom has a distorted octahedral environment with FeN4O2 chromophore. Iron atom is coordinated by two nitrogen atoms from NCS ions, by two oxygen atoms from methanol molecules in the equatorial plane and by two nitrogen atoms of pyridine rings from dpta ligands in axial positions. The crystal lattice forms 2D supramolecular ne

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

—

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

—

Svazek periodika

414

Číslo periodika v rámci svazku

April

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

6

Strana od-do

33-38

Kód UT WoS článku

000334311700006

EID výsledku v databázi Scopus

—