Thermal behavior and decomposition kinetics of ETN and its mixtures with PETN and RDX

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898692" target="_blank" >RIV/00216275:25310/14:39898692 - isvavai.cz</a>

Výsledek na webu

<a href="http://link.springer.com/article/10.1007/s10973-013-3265-2" target="_blank" >http://link.springer.com/article/10.1007/s10973-013-3265-2</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10973-013-3265-2" target="_blank" >10.1007/s10973-013-3265-2</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Thermal behavior and decomposition kinetics of ETN and its mixtures with PETN and RDX

Popis výsledku v původním jazyce

Erythritol tetranitrate (butane-1,2,3,4-tetraol tetranitrate, ETN) has become one of the most synthesized improvised explosives nowadays as it can be found on public internet discussion boards. However, the low melting point, nitrocellulose gelling ability, high energy content, and availability of its precursor make the substance potentially useful in industry as an energetic component or additive in certain gun propellants. Mixtures of ETN with other high explosives are also frequently discussed on webpages dealing with improvised explosives. This article describes thermal behavior and decomposition kinetics of pure ETN and its mixtures with pentaerythritol tetranitrate and cyclonite (1,3,5-trinitro-1,3,5-triazinane, RDX). The thermal behavior and decomposition kinetics of such mixtures are described using non-isothermal DSC and TG techniques. Kissinger method, Soviet manometric method, and modified Kissinger-Akahira-Sunose method were used for data evaluation.

Název v anglickém jazyce

Thermal behavior and decomposition kinetics of ETN and its mixtures with PETN and RDX

Popis výsledku anglicky

Erythritol tetranitrate (butane-1,2,3,4-tetraol tetranitrate, ETN) has become one of the most synthesized improvised explosives nowadays as it can be found on public internet discussion boards. However, the low melting point, nitrocellulose gelling ability, high energy content, and availability of its precursor make the substance potentially useful in industry as an energetic component or additive in certain gun propellants. Mixtures of ETN with other high explosives are also frequently discussed on webpages dealing with improvised explosives. This article describes thermal behavior and decomposition kinetics of pure ETN and its mixtures with pentaerythritol tetranitrate and cyclonite (1,3,5-trinitro-1,3,5-triazinane, RDX). The thermal behavior and decomposition kinetics of such mixtures are described using non-isothermal DSC and TG techniques. Kissinger method, Soviet manometric method, and modified Kissinger-Akahira-Sunose method were used for data evaluation.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/VG20102014032" target="_blank" >VG20102014032: Výzkum detekce improvizovaných výbušin psy</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Thermal Analysis and Calorimetry

ISSN

1388-6150

e-ISSN

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Svazek periodika

115

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

289-299

Kód UT WoS článku

000329621100034

EID výsledku v databázi Scopus

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