Synthesis, crystal structures and properties of coordination polymers from copper(II) adipate

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900112" target="_blank" >RIV/00216275:25310/15:39900112 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1007/s11243-015-9982-6" target="_blank" >http://dx.doi.org/10.1007/s11243-015-9982-6</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11243-015-9982-6" target="_blank" >10.1007/s11243-015-9982-6</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis, crystal structures and properties of coordination polymers from copper(II) adipate

Popis výsledku v původním jazyce

The synthesis, crystal structures and spectroscopy of [{Cu(mu(2)-adip)(benzim)(2)(H2O)}(n)] (1), [{Cu(mu(2)-adip)(4-pyme)(2)(H2O)}(n)] (2), [{Cu(mu(3)-adip)(nia)(2)}(n)center dot nH(2)O] (3), [{Cu(mu(2)-adip)(pydca)(2)}(n)] (4) and [{Cu(mu(4)-adip)(mna)}(n)center dot nH(2)O] (5) (adip = adipate(2-) anion, benzim = benzimidazole, 4-pyme = 4-pyridylmethanol, nia = nicotinamide, pydca = 3,4-pyridinedicarboxamide, mna = N-methylnicotinamide) are reported. The complexes under study were characterized by electronic, IR and EPR spectroscopy, and single-crystal X-ray structure analysis. The complexes form one-dimensional or two-dimensional brick-wall like coordination polymers. The coordination environments around the copper atoms of complexes 1-3 and 5 are distorted tetragonal pyramidal. The copper atom in complex 4 has tetragonal-bipyramidal coordination. Four different coordination modes of adipate ligands in the studied copper(II) complexes were observed. The coordination polymers of the c

Název v anglickém jazyce

Synthesis, crystal structures and properties of coordination polymers from copper(II) adipate

Popis výsledku anglicky

The synthesis, crystal structures and spectroscopy of [{Cu(mu(2)-adip)(benzim)(2)(H2O)}(n)] (1), [{Cu(mu(2)-adip)(4-pyme)(2)(H2O)}(n)] (2), [{Cu(mu(3)-adip)(nia)(2)}(n)center dot nH(2)O] (3), [{Cu(mu(2)-adip)(pydca)(2)}(n)] (4) and [{Cu(mu(4)-adip)(mna)}(n)center dot nH(2)O] (5) (adip = adipate(2-) anion, benzim = benzimidazole, 4-pyme = 4-pyridylmethanol, nia = nicotinamide, pydca = 3,4-pyridinedicarboxamide, mna = N-methylnicotinamide) are reported. The complexes under study were characterized by electronic, IR and EPR spectroscopy, and single-crystal X-ray structure analysis. The complexes form one-dimensional or two-dimensional brick-wall like coordination polymers. The coordination environments around the copper atoms of complexes 1-3 and 5 are distorted tetragonal pyramidal. The copper atom in complex 4 has tetragonal-bipyramidal coordination. Four different coordination modes of adipate ligands in the studied copper(II) complexes were observed. The coordination polymers of the c

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Transition Metal Chemistry

ISSN

0340-4285

e-ISSN

—

Svazek periodika

40

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

12

Strana od-do

857-868

Kód UT WoS článku

000362899400010

EID výsledku v databázi Scopus

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