The first scorpionate ligand based on diazaphosphole

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F15%3A39900319" target="_blank" >RIV/00216275:25310/15:39900319 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1039/C5DT03589A" target="_blank" >http://dx.doi.org/10.1039/C5DT03589A</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C5DT03589A" target="_blank" >10.1039/C5DT03589A</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The first scorpionate ligand based on diazaphosphole

Popis výsledku v původním jazyce

The reaction of PhBCl2 with 1H-1,2,4-?3-diazaphosphole in the presence of NEt3 gives a new scorpionate ligand, phenyl-tris(1,2,4-diazaphospholyl)borate (PhTdap). The coordination behaviour of this ligand toward transition and non-transition metals has been comprehensively studied. In the thallium(I) complex, Tl(PhTdap), ?2-N,N bonding supported with intramolecular ?3-phenyl coordination has been observed in the solid state. Tl(PhTdap) also shows unusual intermolecular ?-interactions between five-membered diazaphosphole rings and the thallium atom giving infinite molecular chains in the crystal. In the square planar complex [Pd(C,N-C6H4CH2NMe2)(PhTdap)], ?2-bonded scorpionate has been detected in both solution and in the solid state. For other studied compounds with the central metal ion Ti(IV), Mo(II), Mn(I), Fe(II), Ru(II), Co(II), Co(III), Ni(II) and Cd(II), the ?3-N,N,N coordination pattern was observed. Electronic properties of PhTdap and its ligand-field strength were elucidated f

Název v anglickém jazyce

The first scorpionate ligand based on diazaphosphole

Popis výsledku anglicky

The reaction of PhBCl2 with 1H-1,2,4-?3-diazaphosphole in the presence of NEt3 gives a new scorpionate ligand, phenyl-tris(1,2,4-diazaphospholyl)borate (PhTdap). The coordination behaviour of this ligand toward transition and non-transition metals has been comprehensively studied. In the thallium(I) complex, Tl(PhTdap), ?2-N,N bonding supported with intramolecular ?3-phenyl coordination has been observed in the solid state. Tl(PhTdap) also shows unusual intermolecular ?-interactions between five-membered diazaphosphole rings and the thallium atom giving infinite molecular chains in the crystal. In the square planar complex [Pd(C,N-C6H4CH2NMe2)(PhTdap)], ?2-bonded scorpionate has been detected in both solution and in the solid state. For other studied compounds with the central metal ion Ti(IV), Mo(II), Mn(I), Fe(II), Ru(II), Co(II), Co(III), Ni(II) and Cd(II), the ?3-N,N,N coordination pattern was observed. Electronic properties of PhTdap and its ligand-field strength were elucidated f

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Dalton Transactions

ISSN

1477-9226

e-ISSN

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Svazek periodika

44

Číslo periodika v rámci svazku

46

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

20242-20253

Kód UT WoS článku

000365402100059

EID výsledku v databázi Scopus

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