Characterization of molecular structure of emulsion acrylic microgels: Exploring the Impact of molar mass on coating properties of self-crosslinkable latexes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901611" target="_blank" >RIV/00216275:25310/16:39901611 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1080/03602559.2016.1185662" target="_blank" >http://dx.doi.org/10.1080/03602559.2016.1185662</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/03602559.2016.1185662" target="_blank" >10.1080/03602559.2016.1185662</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Characterization of molecular structure of emulsion acrylic microgels: Exploring the Impact of molar mass on coating properties of self-crosslinkable latexes

Popis výsledku v původním jazyce

Self-crosslinkable latexes of core?shell microgel particles were synthesized by the emulsion polymerization of acrylic monomers. The molar mass of copolymers forming the shell layer was gradually reduced by isooctyl 3-mercaptopropionate included in the synthesis of the shell layers. The molar mass distribution of latex particles was determined using size exclusion chromatography and asymmetric flow field flow fractionation, respectively, both separation methods being coupled with a multi-angle light scattering detector. The results confirmed theoretical predictions and described empirically the effects of molar mass of the shell layer copolymer on decreasing the minimum film-forming temperature and influencing the end-use properties of coatings.

Název v anglickém jazyce

Characterization of molecular structure of emulsion acrylic microgels: Exploring the Impact of molar mass on coating properties of self-crosslinkable latexes

Popis výsledku anglicky

Self-crosslinkable latexes of core?shell microgel particles were synthesized by the emulsion polymerization of acrylic monomers. The molar mass of copolymers forming the shell layer was gradually reduced by isooctyl 3-mercaptopropionate included in the synthesis of the shell layers. The molar mass distribution of latex particles was determined using size exclusion chromatography and asymmetric flow field flow fractionation, respectively, both separation methods being coupled with a multi-angle light scattering detector. The results confirmed theoretical predictions and described empirically the effects of molar mass of the shell layer copolymer on decreasing the minimum film-forming temperature and influencing the end-use properties of coatings.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polymer-Plastics Technology and Engineering

ISSN

0360-2559

e-ISSN

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Svazek periodika

55

Číslo periodika v rámci svazku

17

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

12

Strana od-do

1807-1818

Kód UT WoS článku

000389037300003

EID výsledku v databázi Scopus

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