Self-Crosslinking Latexes with Improved Flame Stability

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901629" target="_blank" >RIV/00216275:25310/16:39901629 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Self-Crosslinking Latexes with Improved Flame Stability

Popis výsledku v původním jazyce

In this contribution the application of a novel flame retardant based on halogenophosphazene derivative in waterborne coatings based on self-crosslinking latexes was investigated. Hexaallylamino-cyclo-triphosphazene was synthesized by nucleophilic substitution of hexachloro-cyclo-triphosphazene with allyl amine. Latexes of functionalized core-shell particles bearing in the structure a covalently linked hexachloro-cyclo-triphosphazene were prepared by the semi-continuous non-seeded emulsion polymerization of methyl methacrylate, butyl acrylate and methacrylic acid as main monomers. For interfacial crosslinking, diacetone acrylamide was copolymerized into the shell layer of latex particles to provide sites for subsequent reaction with adipic acid dihydrazide. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, toughness and adhesive properties of resulting coatings. Moreover, the presence of the novel flame retardant increased the flame stability of coatings.

Název v anglickém jazyce

Self-Crosslinking Latexes with Improved Flame Stability

Popis výsledku anglicky

In this contribution the application of a novel flame retardant based on halogenophosphazene derivative in waterborne coatings based on self-crosslinking latexes was investigated. Hexaallylamino-cyclo-triphosphazene was synthesized by nucleophilic substitution of hexachloro-cyclo-triphosphazene with allyl amine. Latexes of functionalized core-shell particles bearing in the structure a covalently linked hexachloro-cyclo-triphosphazene were prepared by the semi-continuous non-seeded emulsion polymerization of methyl methacrylate, butyl acrylate and methacrylic acid as main monomers. For interfacial crosslinking, diacetone acrylamide was copolymerized into the shell layer of latex particles to provide sites for subsequent reaction with adipic acid dihydrazide. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, toughness and adhesive properties of resulting coatings. Moreover, the presence of the novel flame retardant increased the flame stability of coatings.

Druh

D - Stať ve sborníku

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

<a href="/cs/project/TE02000011" target="_blank" >TE02000011: Centrum výzkumu povrchových úprav</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

Proceedings of the 4th International Conference on Chemical Technology

ISBN

978-80-86238-94-4

ISSN

2336-811X

e-ISSN

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Počet stran výsledku

6

Strana od-do

325-330

Název nakladatele

Česká společnost průmyslové chemie

Místo vydání

Praha

Místo konání akce

Mikulov

Datum konání akce

25. 4. 2016

Typ akce podle státní příslušnosti

EUR - Evropská akce

Kód UT WoS článku

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