Drying activity of oxovanadium(IV) 2-ethylhexanoate in solvent-borne alkyd paints

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901707" target="_blank" >RIV/00216275:25310/16:39901707 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1007/s11998-015-9779-8" target="_blank" >http://dx.doi.org/10.1007/s11998-015-9779-8</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11998-015-9779-8" target="_blank" >10.1007/s11998-015-9779-8</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Drying activity of oxovanadium(IV) 2-ethylhexanoate in solvent-borne alkyd paints

Popis výsledku v původním jazyce

Oxovanadium(IV) 2-ethylhexanoate was established as a new primary drier for alkyd-based paints. A series of experiments has demonstrated an excellent drying activity toward solvent-borne alkyd resins of different oil length at considerably lower metal concentration than optimal for commercial cobalt(II) 2-ethylhexanoate. The behavior in real paint was simulated on formulations bearing inhibitor of autooxidation. The detailed studies of the drying process have shown that the relatively slow initial step of autooxidation reaction, when compared with cobalt compounds, is compensated for by the absence of the induction times. Furthermore, the active oxovanadium(IV) species are not consumed during the drying processes as evidenced by EPR spectroscopic measurements.

Název v anglickém jazyce

Drying activity of oxovanadium(IV) 2-ethylhexanoate in solvent-borne alkyd paints

Popis výsledku anglicky

Oxovanadium(IV) 2-ethylhexanoate was established as a new primary drier for alkyd-based paints. A series of experiments has demonstrated an excellent drying activity toward solvent-borne alkyd resins of different oil length at considerably lower metal concentration than optimal for commercial cobalt(II) 2-ethylhexanoate. The behavior in real paint was simulated on formulations bearing inhibitor of autooxidation. The detailed studies of the drying process have shown that the relatively slow initial step of autooxidation reaction, when compared with cobalt compounds, is compensated for by the absence of the induction times. Furthermore, the active oxovanadium(IV) species are not consumed during the drying processes as evidenced by EPR spectroscopic measurements.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Coatings Technology Research

ISSN

1945-9645

e-ISSN

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Svazek periodika

13

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

9

Strana od-do

479-487

Kód UT WoS článku

000374677400007

EID výsledku v databázi Scopus

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