4,6-Diazido-N-(2,4,6-trinitrophenyl)-1,3,5-triazin-2-amine (TNADAzT) and Its Silver Salt - Synthesis and Characterization

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911123" target="_blank" >RIV/00216275:25310/17:39911123 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.22211/cejem/70730" target="_blank" >http://dx.doi.org/10.22211/cejem/70730</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.22211/cejem/70730" target="_blank" >10.22211/cejem/70730</a>

Jazyk výsledku

angličtina

Název v původním jazyce

4,6-Diazido-N-(2,4,6-trinitrophenyl)-1,3,5-triazin-2-amine (TNADAzT) and Its Silver Salt - Synthesis and Characterization

Popis výsledku v původním jazyce

4,6-Diazido-N-(2,4,6-trinitrophenyl)-1,3,5-triazin-2-amine (TNADAzT) and its silver salt (AgTNADAzT) were prepared and characterized. Elemental analysis, FTIR, NMR, DSC, AAS and X-ray diffraction were used for analytical characterization. The sensitivities of TNADAzT and AgTNADAzT were determined and compared with common explosives and MTX-1. The crystal density of TNADAzT is 1.794 g.cm(-3) and its heat of formation 899 kJ.mol(-1). The sensitivity of TNADAzT to impact and friction slightly exceeds PETN; the sensitivity to electrostatic discharge is lower than RDX. The sensitivity of AgTNADAzT is on the level of a primary explosives (between mercury fulminate and PETN). The initiation efficiency of AgTNADAzT is higher than 200 mg (acceptor PETN compressed by 64-70 MPa) and therefore excludes it from practical use as a primary explosive in detonators.

Název v anglickém jazyce

4,6-Diazido-N-(2,4,6-trinitrophenyl)-1,3,5-triazin-2-amine (TNADAzT) and Its Silver Salt - Synthesis and Characterization

Popis výsledku anglicky

4,6-Diazido-N-(2,4,6-trinitrophenyl)-1,3,5-triazin-2-amine (TNADAzT) and its silver salt (AgTNADAzT) were prepared and characterized. Elemental analysis, FTIR, NMR, DSC, AAS and X-ray diffraction were used for analytical characterization. The sensitivities of TNADAzT and AgTNADAzT were determined and compared with common explosives and MTX-1. The crystal density of TNADAzT is 1.794 g.cm(-3) and its heat of formation 899 kJ.mol(-1). The sensitivity of TNADAzT to impact and friction slightly exceeds PETN; the sensitivity to electrostatic discharge is lower than RDX. The sensitivity of AgTNADAzT is on the level of a primary explosives (between mercury fulminate and PETN). The initiation efficiency of AgTNADAzT is higher than 200 mg (acceptor PETN compressed by 64-70 MPa) and therefore excludes it from practical use as a primary explosive in detonators.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10406 - Analytical chemistry

Projekt

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Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Central European Journal of Energetic Materials

ISSN

1733-7178

e-ISSN

—

Svazek periodika

14

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

PL - Polská republika

Počet stran výsledku

17

Strana od-do

304-320

Kód UT WoS článku

000404616100004

EID výsledku v databázi Scopus

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