ZnO Coated Anodic 1D TiO2 Nanotube Layers: Efficient Photo-Electrochemical and Gas Sensing Heterojunction

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911320" target="_blank" >RIV/00216275:25310/17:39911320 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/49777513:23220/18:43932787 RIV/68378271:_____/18:00510399

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/10.1002/adem.201700589" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/adem.201700589</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/adem.201700589" target="_blank" >10.1002/adem.201700589</a>

Jazyk výsledku

angličtina

Název v původním jazyce

ZnO Coated Anodic 1D TiO2 Nanotube Layers: Efficient Photo-Electrochemical and Gas Sensing Heterojunction

Popis výsledku v původním jazyce

The authors demonstrate, in this work, a fascinating synergism of a high surface area heterojunction between TiO2 in the form of ordered 1D anodic nanotube layers of a high aspect ratio and ZnO coatings of different thicknesses, produced by atomic layer deposition. The ZnO coatings effectively passivate the defects within the TiO2 nanotube walls and significantly improve their charge carrier separation. Upon the ultraviolet and visible light irradiation, with an increase of the ZnO coating thickness from 0.19 to 19 nm and an increase of the external potential from 0.4–2 V, yields up to 8-fold enhancement of the photocurrent density. This enhancement translates into extremely high incident photon to current conversion efficiency of ≈95%, which is among the highest values reported in the literature for TiO2 based nanostructures. In addition, the photoactive region is expanded to a broader range close to the visible spectral region, compared to the uncoated nanotube layers. Synergistic effect arising from ZnO coated TiO2 nanotube layers also yields an improved ethanol sensing response, almost 11-fold compared to the uncoated nanotube layers. The design of the high-area 1D heterojunction, presented here, opens pathways for the light- and gas-assisted applications in photocatalysis, water splitting, sensors, and so on.

Název v anglickém jazyce

ZnO Coated Anodic 1D TiO2 Nanotube Layers: Efficient Photo-Electrochemical and Gas Sensing Heterojunction

Popis výsledku anglicky

The authors demonstrate, in this work, a fascinating synergism of a high surface area heterojunction between TiO2 in the form of ordered 1D anodic nanotube layers of a high aspect ratio and ZnO coatings of different thicknesses, produced by atomic layer deposition. The ZnO coatings effectively passivate the defects within the TiO2 nanotube walls and significantly improve their charge carrier separation. Upon the ultraviolet and visible light irradiation, with an increase of the ZnO coating thickness from 0.19 to 19 nm and an increase of the external potential from 0.4–2 V, yields up to 8-fold enhancement of the photocurrent density. This enhancement translates into extremely high incident photon to current conversion efficiency of ≈95%, which is among the highest values reported in the literature for TiO2 based nanostructures. In addition, the photoactive region is expanded to a broader range close to the visible spectral region, compared to the uncoated nanotube layers. Synergistic effect arising from ZnO coated TiO2 nanotube layers also yields an improved ethanol sensing response, almost 11-fold compared to the uncoated nanotube layers. The design of the high-area 1D heterojunction, presented here, opens pathways for the light- and gas-assisted applications in photocatalysis, water splitting, sensors, and so on.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

21001 - Nano-materials (production and properties)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Advanced Engineering Materials

ISSN

1438-1656

e-ISSN

1527-2648

Svazek periodika

20

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

10

Strana od-do

"1700589-1"-"1700589-10"

Kód UT WoS článku

000425368600021

EID výsledku v databázi Scopus

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