Role of the Trichlorostannyl Ligand in Tin-Ruthenium Arene Complexes: Experimental and Computational Studies

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911695" target="_blank" >RIV/00216275:25310/17:39911695 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/ejic.201700098" target="_blank" >http://dx.doi.org/10.1002/ejic.201700098</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejic.201700098" target="_blank" >10.1002/ejic.201700098</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Role of the Trichlorostannyl Ligand in Tin-Ruthenium Arene Complexes: Experimental and Computational Studies

Popis výsledku v původním jazyce

A set of neutral and ionic ruthenium arene trichlorostannyl complexes are reported herein. The tin(II)compounds (LSnCl)-Sn-1 {1; L-1 = [2-(CH2NEt2)-4,6-(tBu)(2)C6H2]-} and [(LSnCl)-Sn-2][SnCl3] {2; L-2 = 2,6-[(CH3)C=N(C6H3-2,6-iPr(2))(2)] C5H3N} showed a rather different reactivity towards the ruthenium complex [(eta(6-)cymene)RuCl](2)(eta-Cl)(2). As a consequence, the neutral complex [Ru(eta(6)-cymene)((LSnCl)-Sn-1)Cl-2] (4)and the ionic compound [(LSnCl)-Sn-2][Ru(eta(6)-cymene)(SnCl3)(2)Cl] (8)were isolated. The insertion reaction of 4 with SnCl2 provided the neutral trimetallic ruthenium complex [Ru(eta(6)-cymene)((LSnCl)-Sn-1)(SnCl3)Cl] (6). Analo-gous ruthenium complexes [Ru(eta(6)-cymene)((LPPh2)-P-3)Cl-2] (5)and [Ru(eta 6-cymene)((LPPh2)-P-3)(SnCl3)Cl] (7)containing the phosphane ligand L3PPh2 {3; L-3 = [2,6-iPr(2)-(C6H3)NH](-)} were also prepared to evaluate the donor-acceptor strength of the tin(II)-and phosphorus-containing ligands. The structural characterization and DFT calculations of the above-mentioned complexes suggest a strong influence of the [SnCl3](-)moiety on the Ru-E interaction (E = Sn, P). The influence of the trichlorostannyl ligand on the Ru-E interaction in the complexes 4-7 was further evaluated by means of a distortion/ interaction analysis.

Název v anglickém jazyce

Role of the Trichlorostannyl Ligand in Tin-Ruthenium Arene Complexes: Experimental and Computational Studies

Popis výsledku anglicky

A set of neutral and ionic ruthenium arene trichlorostannyl complexes are reported herein. The tin(II)compounds (LSnCl)-Sn-1 {1; L-1 = [2-(CH2NEt2)-4,6-(tBu)(2)C6H2]-} and [(LSnCl)-Sn-2][SnCl3] {2; L-2 = 2,6-[(CH3)C=N(C6H3-2,6-iPr(2))(2)] C5H3N} showed a rather different reactivity towards the ruthenium complex [(eta(6-)cymene)RuCl](2)(eta-Cl)(2). As a consequence, the neutral complex [Ru(eta(6)-cymene)((LSnCl)-Sn-1)Cl-2] (4)and the ionic compound [(LSnCl)-Sn-2][Ru(eta(6)-cymene)(SnCl3)(2)Cl] (8)were isolated. The insertion reaction of 4 with SnCl2 provided the neutral trimetallic ruthenium complex [Ru(eta(6)-cymene)((LSnCl)-Sn-1)(SnCl3)Cl] (6). Analo-gous ruthenium complexes [Ru(eta(6)-cymene)((LPPh2)-P-3)Cl-2] (5)and [Ru(eta 6-cymene)((LPPh2)-P-3)(SnCl3)Cl] (7)containing the phosphane ligand L3PPh2 {3; L-3 = [2,6-iPr(2)-(C6H3)NH](-)} were also prepared to evaluate the donor-acceptor strength of the tin(II)-and phosphorus-containing ligands. The structural characterization and DFT calculations of the above-mentioned complexes suggest a strong influence of the [SnCl3](-)moiety on the Ru-E interaction (E = Sn, P). The influence of the trichlorostannyl ligand on the Ru-E interaction in the complexes 4-7 was further evaluated by means of a distortion/ interaction analysis.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

—

Svazek periodika

6

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

9

Strana od-do

1292-1300

Kód UT WoS článku

000395786700009

EID výsledku v databázi Scopus

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