Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911700" target="_blank" >RIV/00216275:25310/17:39911700 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds

Popis výsledku v původním jazyce

The chemistry of low-valent main group compounds represents one of the most exciting and quickly developing areas in the field of organometallic and organoelement chemistry. In this context, this chapter is focused on the chemistry of monomeric pnictogen(I) compounds (R-E) (where E = P, As, Sb and Bi), that are known as pnictinidenes. These compounds are elusive and rather reactive substances. It was not possible to isolate them at ambient conditions for a long time except as complexes with various transition metals. This work summarizes most important results achieved during the quest for their synthesis and characterization as transition metal free species. Their coordination by Lewis bases represents the most frequently used way how to fulfill this challenging task, although unique non-coordinated phosphinidenes emerged recently as well. The structure of such base-stabilized pnictinidenes is more or less perturbed in comparison with their elusive parent non-coordinated originals. Nevertheless, their appearance as relatively easy-handling species opened a way for their future investigation and application as model-compounds for &quot;true&quot; pnictinidenes.

Název v anglickém jazyce

Quest for stable or masked pnictinidenes: Emerging and exciting class of group 15 compounds

Popis výsledku anglicky

The chemistry of low-valent main group compounds represents one of the most exciting and quickly developing areas in the field of organometallic and organoelement chemistry. In this context, this chapter is focused on the chemistry of monomeric pnictogen(I) compounds (R-E) (where E = P, As, Sb and Bi), that are known as pnictinidenes. These compounds are elusive and rather reactive substances. It was not possible to isolate them at ambient conditions for a long time except as complexes with various transition metals. This work summarizes most important results achieved during the quest for their synthesis and characterization as transition metal free species. Their coordination by Lewis bases represents the most frequently used way how to fulfill this challenging task, although unique non-coordinated phosphinidenes emerged recently as well. The structure of such base-stabilized pnictinidenes is more or less perturbed in comparison with their elusive parent non-coordinated originals. Nevertheless, their appearance as relatively easy-handling species opened a way for their future investigation and application as model-compounds for &quot;true&quot; pnictinidenes.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GA15-06609S" target="_blank" >GA15-06609S: Organokovové sloučeniny antimonné a bismutné - nová třída ligandů pro přechodné kovy</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Coordination Chemistry Reviews

ISSN

0010-8545

e-ISSN

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Svazek periodika

353

Číslo periodika v rámci svazku

December

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

17

Strana od-do

142-158

Kód UT WoS článku

000417551600004

EID výsledku v databázi Scopus

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