Crystal lattice free volume and thermal decomposition of nitramines
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912320" target="_blank" >RIV/00216275:25310/18:39912320 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.dt.2018.04.012" target="_blank" >http://dx.doi.org/10.1016/j.dt.2018.04.012</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.dt.2018.04.012" target="_blank" >10.1016/j.dt.2018.04.012</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Crystal lattice free volume and thermal decomposition of nitramines
Popis výsledku v původním jazyce
The linear, directly proportional, equations between the Arrhenius parameters (Ea and log A) of the thermal decomposition and the crystal lattice free space per molecule, ΔV, of 22 nitramines are described. It is shown that, because of a significant limitation by the molecular structural characteristics of such compounds, they are divided into a number of partial relationships. These partial relationships divide the nitramines into a group of substances relating to dimethyl nitramine and a sub-group related to ε-NIW. These directly proportional equations mean that an increase in the ΔV values is related to an increase in the thermal stability of the corresponding nitramines. A comparison with similar published dependencies for the impact and friction sensitivities, on the one hand, and with the relationship between the Ea values and the sum of the negative and positive extremes of molecular surface electrostatic potentials, on the other, confirms the well-known fact that intermolecular interaction in the nitramines studied plays a decisive role in the thermal reactivity of such compounds. The crystal lattice free space manifests itself here perhaps only in the solid state thermal decomposition of RDX, HMX and DINGU. This study again confirms a level of disorder in the distribution of the forces in the crystal lattice of the “common” quality of ε-HNIW, compared with its “reduced sensitivity (RS)” or pure analogues.
Název v anglickém jazyce
Crystal lattice free volume and thermal decomposition of nitramines
Popis výsledku anglicky
The linear, directly proportional, equations between the Arrhenius parameters (Ea and log A) of the thermal decomposition and the crystal lattice free space per molecule, ΔV, of 22 nitramines are described. It is shown that, because of a significant limitation by the molecular structural characteristics of such compounds, they are divided into a number of partial relationships. These partial relationships divide the nitramines into a group of substances relating to dimethyl nitramine and a sub-group related to ε-NIW. These directly proportional equations mean that an increase in the ΔV values is related to an increase in the thermal stability of the corresponding nitramines. A comparison with similar published dependencies for the impact and friction sensitivities, on the one hand, and with the relationship between the Ea values and the sum of the negative and positive extremes of molecular surface electrostatic potentials, on the other, confirms the well-known fact that intermolecular interaction in the nitramines studied plays a decisive role in the thermal reactivity of such compounds. The crystal lattice free space manifests itself here perhaps only in the solid state thermal decomposition of RDX, HMX and DINGU. This study again confirms a level of disorder in the distribution of the forces in the crystal lattice of the “common” quality of ε-HNIW, compared with its “reduced sensitivity (RS)” or pure analogues.
Klasifikace
Druh
J<sub>SC</sub> - Článek v periodiku v databázi SCOPUS
CEP obor
—
OECD FORD obor
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2018
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Defence Technology
ISSN
2214-9147
e-ISSN
—
Svazek periodika
15
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
CN - Čínská lidová republika
Počet stran výsledku
7
Strana od-do
51-57
Kód UT WoS článku
000457214100005
EID výsledku v databázi Scopus
2-s2.0-85047555066