Novel dibenzothiophene chromophores with peripheral barbituric acceptors

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39914555" target="_blank" >RIV/00216275:25310/19:39914555 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0040402019307598?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0040402019307598?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.tet.2019.07.017" target="_blank" >10.1016/j.tet.2019.07.017</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Novel dibenzothiophene chromophores with peripheral barbituric acceptors

Popis výsledku v původním jazyce

A series of novel chromophores based on central 2,8-disubstituted dibenzothiophene (DBT) or dibenzothiophene-S,S-dioxide (DBTO) has been designed and prepared. The interconnection of DBT(O) central scaffold with two peripheral barbituric acceptors via various pi-spacer allowed significant property tuning of target chromophores. Four new final chromophores and six DBT(O)-intermediates have been successfully synthesized and fully characterized. Experimental and calculated data showed that the fundamental properties are affected by the chromophore A-pi-D-pi-A or A-pi-A-pi-A arrangement (DBT vs. DBTO) and the pi-linker (ethenylene vs. ethynylene). Thorough structure-property relationships have been elucidated and discussed in detail.

Název v anglickém jazyce

Novel dibenzothiophene chromophores with peripheral barbituric acceptors

Popis výsledku anglicky

A series of novel chromophores based on central 2,8-disubstituted dibenzothiophene (DBT) or dibenzothiophene-S,S-dioxide (DBTO) has been designed and prepared. The interconnection of DBT(O) central scaffold with two peripheral barbituric acceptors via various pi-spacer allowed significant property tuning of target chromophores. Four new final chromophores and six DBT(O)-intermediates have been successfully synthesized and fully characterized. Experimental and calculated data showed that the fundamental properties are affected by the chromophore A-pi-D-pi-A or A-pi-A-pi-A arrangement (DBT vs. DBTO) and the pi-linker (ethenylene vs. ethynylene). Thorough structure-property relationships have been elucidated and discussed in detail.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Tetrahedron

ISSN

0040-4020

e-ISSN

—

Svazek periodika

75

Číslo periodika v rámci svazku

34

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

"130459-1"-"130459-10"

Kód UT WoS článku

000482244700005

EID výsledku v databázi Scopus

2-s2.0-85069049535