Synthetic development in Cd–Zn–Se quantum dots chemistry

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39914843" target="_blank" >RIV/00216275:25310/19:39914843 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216305:26620/19:PU135048

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0925346719306056?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0925346719306056?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.optmat.2019.109385" target="_blank" >10.1016/j.optmat.2019.109385</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthetic development in Cd–Zn–Se quantum dots chemistry

Popis výsledku v původním jazyce

Despite a great number of studies devoted to the synthesis of chalcogenide quantum dots (QDs), many essential questions remain open up to date. Primarily, it is a safety of the synthesis, both in the laboratory and in the industry. Another issue is the reproducibility of QDs with desired characteristics. And, without doubt, the ability to adjust properties of the resulting QDs by the implementation of various approaches to the synthesis is significant. Here we provide a novel approach to the synthesis of ternary Cd–Zn–Se QDs (ratios Cd: Zn=10 : 90; 25 : 75; 50 : 50; 75 : 25; 90 : 10) using disubstituted selenourea as a novel source of selenium. (Z)-1-hexyl-3- (octadec-9-enyl)selenourea was synthesized in three steps with a good yield of the final product. It opens up a simple, convenient and environmentally friendly way to the synthesis of the selected QDs. Varying the molar ratios of Cd and Zn, QDs of different composition were produced in high yields. According to the conducted research, highly photoluminescent ternary Cd–Zn–Se QDs (photoluminescent quantum yield PL QY up to 64%) are uniform, both in elemental composition and in size (3.6–5.3 nm). Moreover, the selection of given selenourea made it possible to scale the synthesis by 24 times with an increase in the amount of QDs without loss of product quality. This demonstrates the feasibility to produce such type of materials on an industrial scale.

Název v anglickém jazyce

Synthetic development in Cd–Zn–Se quantum dots chemistry

Popis výsledku anglicky

Despite a great number of studies devoted to the synthesis of chalcogenide quantum dots (QDs), many essential questions remain open up to date. Primarily, it is a safety of the synthesis, both in the laboratory and in the industry. Another issue is the reproducibility of QDs with desired characteristics. And, without doubt, the ability to adjust properties of the resulting QDs by the implementation of various approaches to the synthesis is significant. Here we provide a novel approach to the synthesis of ternary Cd–Zn–Se QDs (ratios Cd: Zn=10 : 90; 25 : 75; 50 : 50; 75 : 25; 90 : 10) using disubstituted selenourea as a novel source of selenium. (Z)-1-hexyl-3- (octadec-9-enyl)selenourea was synthesized in three steps with a good yield of the final product. It opens up a simple, convenient and environmentally friendly way to the synthesis of the selected QDs. Varying the molar ratios of Cd and Zn, QDs of different composition were produced in high yields. According to the conducted research, highly photoluminescent ternary Cd–Zn–Se QDs (photoluminescent quantum yield PL QY up to 64%) are uniform, both in elemental composition and in size (3.6–5.3 nm). Moreover, the selection of given selenourea made it possible to scale the synthesis by 24 times with an increase in the amount of QDs without loss of product quality. This demonstrates the feasibility to produce such type of materials on an industrial scale.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Optical Materials

ISSN

0925-3467

e-ISSN

—

Svazek periodika

97

Číslo periodika v rámci svazku

November

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

"109385-1"-"109385-9"

Kód UT WoS článku

000501396600016

EID výsledku v databázi Scopus

2-s2.0-85072263559