1.5 mu m photoluminescence and upconversion photoluminescence in GeGaAsS:Er chalcogenide glass

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39914986" target="_blank" >RIV/00216275:25310/19:39914986 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.1515/pac-2018-1231" target="_blank" >https://doi.org/10.1515/pac-2018-1231</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1515/pac-2018-1231" target="_blank" >10.1515/pac-2018-1231</a>

Jazyk výsledku

angličtina

Název v původním jazyce

1.5 mu m photoluminescence and upconversion photoluminescence in GeGaAsS:Er chalcogenide glass

Popis výsledku v původním jazyce

The paper reports on ≈1.5 μm Stokes photoluminescence (PL) emission and upconversion photoluminescence (UCPL) emission in the visible and near-infrared spectral region in Er3+-doped Ge25Ga8As2S65 chalcogenide glasses at pumping wavelengths of 980 and 1550 nm. The ≈1.5 μm PL emission spectra are broadened with increasing concentration of Er ions which is discussed in terms of radiation trapping and UCPL dynamics affecting the Er3+: 4I13/2 level lifetime. The UCPL emission was observed at ≈530, ≈550, ≈660, ≈810 and ≈990 nm and its overall intensity as well as red-to-green UCPL emission intensity ratio increases with increasing Er concentration. To explore the UCPL dynamics we measured double logarithmic dependency of green (≈550 nm) and red (≈660 nm) UCPL emission versus pump power at pumping wavelength of 975 nm. Moreover, we measured quadrature frequency resolved spectroscopy (QFRS) on green UCPL emission (≈550 nm) using 975 nm pumping wavelength and various excitation powers. The QFRS spectra on green UCPL were analyzed in term of QFRS transfer function for three-level model from which we deduced energy transfer upconversion rate w11 (s-1) originating from Er3+: 4I11/2, 4I11/2→4F7/2, 4I15/2 transitions.

Název v anglickém jazyce

1.5 mu m photoluminescence and upconversion photoluminescence in GeGaAsS:Er chalcogenide glass

Popis výsledku anglicky

The paper reports on ≈1.5 μm Stokes photoluminescence (PL) emission and upconversion photoluminescence (UCPL) emission in the visible and near-infrared spectral region in Er3+-doped Ge25Ga8As2S65 chalcogenide glasses at pumping wavelengths of 980 and 1550 nm. The ≈1.5 μm PL emission spectra are broadened with increasing concentration of Er ions which is discussed in terms of radiation trapping and UCPL dynamics affecting the Er3+: 4I13/2 level lifetime. The UCPL emission was observed at ≈530, ≈550, ≈660, ≈810 and ≈990 nm and its overall intensity as well as red-to-green UCPL emission intensity ratio increases with increasing Er concentration. To explore the UCPL dynamics we measured double logarithmic dependency of green (≈550 nm) and red (≈660 nm) UCPL emission versus pump power at pumping wavelength of 975 nm. Moreover, we measured quadrature frequency resolved spectroscopy (QFRS) on green UCPL emission (≈550 nm) using 975 nm pumping wavelength and various excitation powers. The QFRS spectra on green UCPL were analyzed in term of QFRS transfer function for three-level model from which we deduced energy transfer upconversion rate w11 (s-1) originating from Er3+: 4I11/2, 4I11/2→4F7/2, 4I15/2 transitions.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Pure and Applied Chemistry

ISSN

0033-4545

e-ISSN

1365-3075

Svazek periodika

91

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

11

Strana od-do

1757-1767

Kód UT WoS článku

000496795300006

EID výsledku v databázi Scopus

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