Thermoelectric Properties of FeSb2Te Based Ternary Skutterudites with Mo Nanoinclusions
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F19%3A39915214" target="_blank" >RIV/00216275:25310/19:39915214 - isvavai.cz</a>
Výsledek na webu
<a href="http://www.materialstoday.com/proceedings" target="_blank" >http://www.materialstoday.com/proceedings</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.matpr.2019.02.058" target="_blank" >10.1016/j.matpr.2019.02.058</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Thermoelectric Properties of FeSb2Te Based Ternary Skutterudites with Mo Nanoinclusions
Popis výsledku v původním jazyce
Polycrystalline samples of FeSb2Te ternary skutterudite based compounds were prepared by the powder metallurgy method. The influence of additions of Mo nanoparticles into host-matrix compound (FeSb2Te) was investigated. Wet blending route (ultrasonication/rotavapor) was used to obtain homogeneous dispersion of the host-matrix compound with Mo nanoparticles. The nanocomposite powders FeSb2Te+x vol.% Mo (x=0, 2, 4, 6) were hot-pressed for 1hr at 500°C/70 MPa. The prepared p-type samples were characterized by measurements of their electrical conductivity, Seebeck coefficient, and thermal conductivity. SEM and EDX results revealed Mo nanoparticles mainly inside of intergrain space of the host-matrix material. Strikingly, Mo does not react with the matrix material. The presence of the Mo nanoparticles in the intergrain space appears to reduce phonon mean free path resulting in a reduction of the thermal conductivity of the studied nanocomposite materials. The extra scattering of phonons on the embedded Mo nanoparticles is responsible for about 20% increase of ZT at some of the nanocomposite samples.
Název v anglickém jazyce
Thermoelectric Properties of FeSb2Te Based Ternary Skutterudites with Mo Nanoinclusions
Popis výsledku anglicky
Polycrystalline samples of FeSb2Te ternary skutterudite based compounds were prepared by the powder metallurgy method. The influence of additions of Mo nanoparticles into host-matrix compound (FeSb2Te) was investigated. Wet blending route (ultrasonication/rotavapor) was used to obtain homogeneous dispersion of the host-matrix compound with Mo nanoparticles. The nanocomposite powders FeSb2Te+x vol.% Mo (x=0, 2, 4, 6) were hot-pressed for 1hr at 500°C/70 MPa. The prepared p-type samples were characterized by measurements of their electrical conductivity, Seebeck coefficient, and thermal conductivity. SEM and EDX results revealed Mo nanoparticles mainly inside of intergrain space of the host-matrix material. Strikingly, Mo does not react with the matrix material. The presence of the Mo nanoparticles in the intergrain space appears to reduce phonon mean free path resulting in a reduction of the thermal conductivity of the studied nanocomposite materials. The extra scattering of phonons on the embedded Mo nanoparticles is responsible for about 20% increase of ZT at some of the nanocomposite samples.
Klasifikace
Druh
D - Stať ve sborníku
CEP obor
—
OECD FORD obor
10402 - Inorganic and nuclear chemistry
Návaznosti výsledku
Projekt
<a href="/cs/project/GA16-07711S" target="_blank" >GA16-07711S: Systematická studie vlivu výšky Schottkyho bariéry na energetické filtrování elektronů v termoelektrických nanokompozitech.</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2019
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název statě ve sborníku
Materials Today : Proceedings
ISBN
—
ISSN
2214-7853
e-ISSN
—
Počet stran výsledku
8
Strana od-do
592-599
Název nakladatele
Elsevier
Místo vydání
Kidlington
Místo konání akce
Padova
Datum konání akce
25. 9. 2017
Typ akce podle státní příslušnosti
EUR - Evropská akce
Kód UT WoS článku
000468329300012