The influence of vegetable oils composition on separation of transesterification products, especially quality of glycerol

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F21%3A39918017" target="_blank" >RIV/00216275:25310/21:39918017 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0960148121007266?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0960148121007266?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.renene.2021.05.050" target="_blank" >10.1016/j.renene.2021.05.050</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The influence of vegetable oils composition on separation of transesterification products, especially quality of glycerol

Popis výsledku v původním jazyce

The paper describes the properties of glycerol produced by transesterification, especially the ester content in the glycerol phase (ester losses) including the distribution of esters according to higher fatty acids. Glycerol, produced by transesterification of oil as a side product -the polar glycerol phase, is an important chemical raw material. The decreasing of ester losses is important because it (i) increases the ester yield and especially (ii) decreases the cost of glycerol purification. The transesterification of oils (rapeseed, olive, palm, sunflower and Camelina Sativa) with various distributions of fatty acids was carried out by methanol, ethanol and butanol including different transesterification stopping. The losses of ethyl and butyl esters are much higher than losses of methyl ester (approximately 2-3x). The dis-tribution of ethyl and butyl esters in the glycerol phase is the same as in the ester phase, whereas distribution of methyl ester is different and depends on the way of transesterification stopping. The reason is the different polarity of methyl esters, which depends on the type of fatty acid. The polarity increases with increasing of double bonds, i.e. the most soluble is methyl ester of linolenic acid in the glycerol phase. (c) 2021 Elsevier Ltd. All rights reserved.

Název v anglickém jazyce

The influence of vegetable oils composition on separation of transesterification products, especially quality of glycerol

Popis výsledku anglicky

The paper describes the properties of glycerol produced by transesterification, especially the ester content in the glycerol phase (ester losses) including the distribution of esters according to higher fatty acids. Glycerol, produced by transesterification of oil as a side product -the polar glycerol phase, is an important chemical raw material. The decreasing of ester losses is important because it (i) increases the ester yield and especially (ii) decreases the cost of glycerol purification. The transesterification of oils (rapeseed, olive, palm, sunflower and Camelina Sativa) with various distributions of fatty acids was carried out by methanol, ethanol and butanol including different transesterification stopping. The losses of ethyl and butyl esters are much higher than losses of methyl ester (approximately 2-3x). The dis-tribution of ethyl and butyl esters in the glycerol phase is the same as in the ester phase, whereas distribution of methyl ester is different and depends on the way of transesterification stopping. The reason is the different polarity of methyl esters, which depends on the type of fatty acid. The polarity increases with increasing of double bonds, i.e. the most soluble is methyl ester of linolenic acid in the glycerol phase. (c) 2021 Elsevier Ltd. All rights reserved.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Renewable Energy

ISSN

0960-1481

e-ISSN

—

Svazek periodika

176

Číslo periodika v rámci svazku

October

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

7

Strana od-do

262-268

Kód UT WoS článku

000660471800006

EID výsledku v databázi Scopus

2-s2.0-85106559945