Anodic TiO2 nanotube walls reconstructed: Inner wall replaced by ALD TiO2 coating
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F21%3A39918168" target="_blank" >RIV/00216275:25310/21:39918168 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/00216305:26620/21:PU141850
Výsledek na webu
<a href="https://www.sciencedirect.com/science/article/pii/S0169433221003822" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0169433221003822</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.apsusc.2021.149306" target="_blank" >10.1016/j.apsusc.2021.149306</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Anodic TiO2 nanotube walls reconstructed: Inner wall replaced by ALD TiO2 coating
Popis výsledku v původním jazyce
A reconstruction process of TiO2 nanotube (TNT) layers towards their superior photoelectrochemical performance and photocatalytic activity is presented. At first, TNT layers (similar to 5 mu m thick, similar to 250 nm in diameter) were prepared via electrochemical anodization to obtain double-wall (DW) TNT layers. Second, a selective chemical treatment was conducted to etch the inner wall, yielding single-wall (SW) TNT layers. Third, TNT layers were coated by an additional approx. 5.5 nm, 11 nm, and 16 nm thick TiO2 coatings, respectively, using Atomic Layer Deposition (ALD). A pronounced increase in the incident photon-to-electron conversion efficiency (reaching similar to 85% at lambda - 350 nm) was achieved on SW TNT layers coated with 11 nm thick ALD coatings compared to SW without coating (similar to 35% at lambda = 350 nm). This is due to the optimal thickness of the ALD TiO2 coating that passivates surface states and improves the separation of the photogenerated charge carriers. Photocatalytic performance of SW TNT layers with 11 nm thick ALD coatings (rate constant; k = 0.1156 min(-1)) was increased by approx. 10-times compared to that of the nowadays most reported blank DW TNT layers (rate constant; k = 0.0119 min(-1)).
Název v anglickém jazyce
Anodic TiO2 nanotube walls reconstructed: Inner wall replaced by ALD TiO2 coating
Popis výsledku anglicky
A reconstruction process of TiO2 nanotube (TNT) layers towards their superior photoelectrochemical performance and photocatalytic activity is presented. At first, TNT layers (similar to 5 mu m thick, similar to 250 nm in diameter) were prepared via electrochemical anodization to obtain double-wall (DW) TNT layers. Second, a selective chemical treatment was conducted to etch the inner wall, yielding single-wall (SW) TNT layers. Third, TNT layers were coated by an additional approx. 5.5 nm, 11 nm, and 16 nm thick TiO2 coatings, respectively, using Atomic Layer Deposition (ALD). A pronounced increase in the incident photon-to-electron conversion efficiency (reaching similar to 85% at lambda - 350 nm) was achieved on SW TNT layers coated with 11 nm thick ALD coatings compared to SW without coating (similar to 35% at lambda = 350 nm). This is due to the optimal thickness of the ALD TiO2 coating that passivates surface states and improves the separation of the photogenerated charge carriers. Photocatalytic performance of SW TNT layers with 11 nm thick ALD coatings (rate constant; k = 0.1156 min(-1)) was increased by approx. 10-times compared to that of the nowadays most reported blank DW TNT layers (rate constant; k = 0.0119 min(-1)).
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Návaznosti výsledku
Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2021
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Applied Surface Science
ISSN
0169-4332
e-ISSN
1873-5584
Svazek periodika
549
Číslo periodika v rámci svazku
May
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
8
Strana od-do
149306
Kód UT WoS článku
000630051900001
EID výsledku v databázi Scopus
2-s2.0-85101076278