Characterisation of carbon paste electrodes bulk-modified with surfactants for measurements in nonaqueous media
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F22%3A39916076" target="_blank" >RIV/00216275:25310/22:39916076 - isvavai.cz</a>
Výsledek na webu
<a href="https://www.sciencedirect.com/science/article/pii/S0013468622002195" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0013468622002195</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2022.140047" target="_blank" >10.1016/j.electacta.2022.140047</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Characterisation of carbon paste electrodes bulk-modified with surfactants for measurements in nonaqueous media
Popis výsledku v původním jazyce
This article deals with carbon paste electrodes bulk-modified with surfactants for measurements in pure organic solvents where common carbon paste-based mixtures undergo disintegration. The electrodes of interest were prepared by mixing of selected carbon materials (namely: two types of graphite powder, glassy carbon powder, raw shungite powder, and multi-wall carbon nanotubes, with various binders (mineral oil, silicone oil, paraffin wax, vaseline, atactic polypropylene, and tricresyl phosphate), together with surfactants of choice (sodium dodecyl sulfate, cetylpyridinium chloride, benzethonium chloride, cetyltrimethylammonium bromide, didodecyldimethylammonium bromide, Triton X-100, and 1,3‒didecyl‒2‒methylimidazolium chloride). The corresponding studies were focused on the optimal composition of the individual pastes and their characterisation in organic solvents, when using cyclic voltammetry with model redox pairs (ferrocenium/ferrocene and quinone/hydroquinone). The results obtained suggest one that amount of the individual components depends predominantly on the type of carbon used. Key factors for selection of the proper surfactant are its polarity, chemical inertness, and electrochemical inactivity. For comparison, glassy carbon disc electrode was also used.
Název v anglickém jazyce
Characterisation of carbon paste electrodes bulk-modified with surfactants for measurements in nonaqueous media
Popis výsledku anglicky
This article deals with carbon paste electrodes bulk-modified with surfactants for measurements in pure organic solvents where common carbon paste-based mixtures undergo disintegration. The electrodes of interest were prepared by mixing of selected carbon materials (namely: two types of graphite powder, glassy carbon powder, raw shungite powder, and multi-wall carbon nanotubes, with various binders (mineral oil, silicone oil, paraffin wax, vaseline, atactic polypropylene, and tricresyl phosphate), together with surfactants of choice (sodium dodecyl sulfate, cetylpyridinium chloride, benzethonium chloride, cetyltrimethylammonium bromide, didodecyldimethylammonium bromide, Triton X-100, and 1,3‒didecyl‒2‒methylimidazolium chloride). The corresponding studies were focused on the optimal composition of the individual pastes and their characterisation in organic solvents, when using cyclic voltammetry with model redox pairs (ferrocenium/ferrocene and quinone/hydroquinone). The results obtained suggest one that amount of the individual components depends predominantly on the type of carbon used. Key factors for selection of the proper surfactant are its polarity, chemical inertness, and electrochemical inactivity. For comparison, glassy carbon disc electrode was also used.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Návaznosti výsledku
Projekt
—
Návaznosti
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2022
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Electrochimica Acta
ISSN
0013-4686
e-ISSN
1873-3859
Svazek periodika
410
Číslo periodika v rámci svazku
April
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
8
Strana od-do
140047
Kód UT WoS článku
000782653000004
EID výsledku v databázi Scopus
2-s2.0-85124799366