Enhanced Removal of Arsenic from Aqueous Medium by Modified Silica Nanospheres: Kinetic and Thermodynamic Studies

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F22%3A39917746" target="_blank" >RIV/00216275:25310/22:39917746 - isvavai.cz</a>

Výsledek na webu

<a href="https://link.springer.com/article/10.1007%2Fs13369-021-05357-5" target="_blank" >https://link.springer.com/article/10.1007%2Fs13369-021-05357-5</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s13369-021-05357-5" target="_blank" >10.1007/s13369-021-05357-5</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Enhanced Removal of Arsenic from Aqueous Medium by Modified Silica Nanospheres: Kinetic and Thermodynamic Studies

Popis výsledku v původním jazyce

In this study, silica nanospheres (S) and trizma base-modified silica nanospheres (ST2, ST4, ST6, and ST8) were synthesized for the removal of arsenic from aqueous medium with high efficiency. Characterization of the prepared solid adsorbents was performed with different techniques such as thermogravimetric analysis, scanning electron microscopy, X-ray diffraction patterns, transmission electron microscopy, selected area electron diffraction, fast Fourier transform, nitrogen adsorption, point of zero charge (pH(PZC)), and Fourier transform infrared. Adsorption of As+5 was investigated under different application conditions such as adsorbent dosage, pH, shaking time, temperature, and initial As+5 concentration. Maximum adsorption capacity reached 64.5 mg/g at pH 6, 0.9 g/L as adsorbent dosage, after 60 min of shaking time, and at 25 degrees C as the optimum adsorption conditions. Adsorption data of As+5 by the prepared nanoadsorbents are best fitted with Langmuir, Temkin, and Dubinin-Radushkevich models. Kinetic studies revealed that the adsorption followed pseudo-second-order and Elovich kinetic models. Thermodynamic studies prove that the adsorption process is endothermic, spontaneous, and chemisorption in nature. The most effective desorption was achieved by nitric acid with 99% desorption efficiency. The prepared silica nanospheres solid adsorbents showed a good reusability with 91% adsorption efficiency after four cycles of adsorption and desorption.

Název v anglickém jazyce

Enhanced Removal of Arsenic from Aqueous Medium by Modified Silica Nanospheres: Kinetic and Thermodynamic Studies

Popis výsledku anglicky

In this study, silica nanospheres (S) and trizma base-modified silica nanospheres (ST2, ST4, ST6, and ST8) were synthesized for the removal of arsenic from aqueous medium with high efficiency. Characterization of the prepared solid adsorbents was performed with different techniques such as thermogravimetric analysis, scanning electron microscopy, X-ray diffraction patterns, transmission electron microscopy, selected area electron diffraction, fast Fourier transform, nitrogen adsorption, point of zero charge (pH(PZC)), and Fourier transform infrared. Adsorption of As+5 was investigated under different application conditions such as adsorbent dosage, pH, shaking time, temperature, and initial As+5 concentration. Maximum adsorption capacity reached 64.5 mg/g at pH 6, 0.9 g/L as adsorbent dosage, after 60 min of shaking time, and at 25 degrees C as the optimum adsorption conditions. Adsorption data of As+5 by the prepared nanoadsorbents are best fitted with Langmuir, Temkin, and Dubinin-Radushkevich models. Kinetic studies revealed that the adsorption followed pseudo-second-order and Elovich kinetic models. Thermodynamic studies prove that the adsorption process is endothermic, spontaneous, and chemisorption in nature. The most effective desorption was achieved by nitric acid with 99% desorption efficiency. The prepared silica nanospheres solid adsorbents showed a good reusability with 91% adsorption efficiency after four cycles of adsorption and desorption.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Arabian Journal for Science and Engineering

ISSN

2193-567X

e-ISSN

2191-4281

Svazek periodika

47

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

13

Strana od-do

281-293

Kód UT WoS článku

000611916100001

EID výsledku v databázi Scopus

2-s2.0-85099933023