Utilization of CO2-Available Organocatalysts for Reactions with Industrially Important Epoxides

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F22%3A39919216" target="_blank" >RIV/00216275:25310/22:39919216 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.mdpi.com/2073-4344/12/3/298" target="_blank" >https://www.mdpi.com/2073-4344/12/3/298</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal12030298" target="_blank" >10.3390/catal12030298</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Utilization of CO2-Available Organocatalysts for Reactions with Industrially Important Epoxides

Popis výsledku v původním jazyce

Recent knowledge in chemistry has enabled the material utilization of greenhouse gas (CO2) for the production of organic carbonates using mild reaction conditions. Organic carbonates, especially cyclic carbonates, are applicable as green solvents, electrolytes in batteries, feedstock for fine chemicals and monomers for polycarbonate production. This review summarizes new developments in the ring opening of epoxides with subsequent CO2-based formation of cyclic carbonates. The review highlights recent and major developments for sustainable CO2 conversion from 2000 to the end of 2021 abstracted by Web of Science. The syntheses of epoxides, especially from bio-based raw materials, will be summarized, such as the types of raw material (vegetable oils or their esters) and the reaction conditions. The aim of this review is also to summarize and to compare the types of homogeneous non-metallic catalysts. The three reaction mechanisms for cyclic carbonate formation are presented, namely activation of the epoxide ring, CO2 activation and dual activation.

Název v anglickém jazyce

Utilization of CO2-Available Organocatalysts for Reactions with Industrially Important Epoxides

Popis výsledku anglicky

Recent knowledge in chemistry has enabled the material utilization of greenhouse gas (CO2) for the production of organic carbonates using mild reaction conditions. Organic carbonates, especially cyclic carbonates, are applicable as green solvents, electrolytes in batteries, feedstock for fine chemicals and monomers for polycarbonate production. This review summarizes new developments in the ring opening of epoxides with subsequent CO2-based formation of cyclic carbonates. The review highlights recent and major developments for sustainable CO2 conversion from 2000 to the end of 2021 abstracted by Web of Science. The syntheses of epoxides, especially from bio-based raw materials, will be summarized, such as the types of raw material (vegetable oils or their esters) and the reaction conditions. The aim of this review is also to summarize and to compare the types of homogeneous non-metallic catalysts. The three reaction mechanisms for cyclic carbonate formation are presented, namely activation of the epoxide ring, CO2 activation and dual activation.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10511 - Environmental sciences (social aspects to be 5.7)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

2073-4344

Svazek periodika

12

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

41

Strana od-do

298

Kód UT WoS článku

000776896900001

EID výsledku v databázi Scopus

2-s2.0-85126032254