The influence of residue sodium ions in mixed oxide on catalytic activity in transesterification of vegetable oil

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F22%3A39919512" target="_blank" >RIV/00216275:25310/22:39919512 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/62243136:_____/21:N0000016

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2468823121006337" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2468823121006337</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mcat.2021.112017" target="_blank" >10.1016/j.mcat.2021.112017</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The influence of residue sodium ions in mixed oxide on catalytic activity in transesterification of vegetable oil

Popis výsledku v původním jazyce

The Mg-Al mixed oxides are an attractive acid-base catalyst with various activity published even for the same reaction under similar conditions. The differences in the results can be caused by impurities remaining after synthesis, which is very often omitted in papers. The influence of remaining sodium impurities (from 5 to 345 mu mol/g of hydrotalcite) on the catalysed transesterification of vegetable oil was studied. The novelty consists in the detailed description of the transformation of sodium species throughout synthesis of mixed oxides: the sodium nitrates, presented in hydrotalcites, were transformed to sodium oxide (during calcination), which reacted with water (present in oil and methanol) to sodium hydroxides. During transesterification, the sodium hydroxide leached to the liquid phase and so increased the ester yield as a homogeneous catalyst. The ester content was only 19 wt.% with the catalyst containing almost no sodium ions (5 mu mol/g), but only 18 mu mol/g caused increasing of ester content to 50 wt.%. Moreover, the sodium compounds rapidly increased the catalyst activity by changing the active sites. The reusability of the catalyst was caried out and the ester content decreased to only 22% after four cycles, because the sodium leached.

Název v anglickém jazyce

The influence of residue sodium ions in mixed oxide on catalytic activity in transesterification of vegetable oil

Popis výsledku anglicky

The Mg-Al mixed oxides are an attractive acid-base catalyst with various activity published even for the same reaction under similar conditions. The differences in the results can be caused by impurities remaining after synthesis, which is very often omitted in papers. The influence of remaining sodium impurities (from 5 to 345 mu mol/g of hydrotalcite) on the catalysed transesterification of vegetable oil was studied. The novelty consists in the detailed description of the transformation of sodium species throughout synthesis of mixed oxides: the sodium nitrates, presented in hydrotalcites, were transformed to sodium oxide (during calcination), which reacted with water (present in oil and methanol) to sodium hydroxides. During transesterification, the sodium hydroxide leached to the liquid phase and so increased the ester yield as a homogeneous catalyst. The ester content was only 19 wt.% with the catalyst containing almost no sodium ions (5 mu mol/g), but only 18 mu mol/g caused increasing of ester content to 50 wt.%. Moreover, the sodium compounds rapidly increased the catalyst activity by changing the active sites. The reusability of the catalyst was caried out and the ester content decreased to only 22% after four cycles, because the sodium leached.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/GA19-00669S" target="_blank" >GA19-00669S: Vztahy mezi aktivitou a strukturou Mg-Al/Fe směsných oxidů včetně post-syntetických úprav v transesterifikaci a Guerbetově reakci</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Molecular Catalysis

ISSN

2468-8231

e-ISSN

2468-8231

Svazek periodika

517

Číslo periodika v rámci svazku

January

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

10

Strana od-do

"112017-1"-"112017-10"

Kód UT WoS článku

000737631400010

EID výsledku v databázi Scopus

2-s2.0-85120444627