Characterization and properties of layered tetragonal metal phosphonates with Sulfoethyl and Sulfophenyl groups.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F23%3A39920228" target="_blank" >RIV/00216275:25310/23:39920228 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0167273823001157?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0167273823001157?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.ssi.2023.116257" target="_blank" >10.1016/j.ssi.2023.116257</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Characterization and properties of layered tetragonal metal phosphonates with Sulfoethyl and Sulfophenyl groups.

Popis výsledku v původním jazyce

A set of five tetravalent metal phosphonates, zirconium 2-sulfoethylphosphonate, titanium and tin 4-sulfophenylphosphonates, and mixed titanium and tin 4-sulfophenylphosphonate-phosphates, were prepared and characterized. All compounds are layered, their inorganic part is similar to that of α-zirconium hydrogen phosphate with the sulfophenyl or sulfoethyl groups jutting out of the layers into the interlayer space. Ionic conductivity of zirconium 2-sulfoethylphosphonate, titanium and tin 4-sulfophenylphosphonate strongly depends on relative humidity. The charge carriers are protons and their movement is governed by a Grotthuss mechanism.

Název v anglickém jazyce

Characterization and properties of layered tetragonal metal phosphonates with Sulfoethyl and Sulfophenyl groups.

Popis výsledku anglicky

A set of five tetravalent metal phosphonates, zirconium 2-sulfoethylphosphonate, titanium and tin 4-sulfophenylphosphonates, and mixed titanium and tin 4-sulfophenylphosphonate-phosphates, were prepared and characterized. All compounds are layered, their inorganic part is similar to that of α-zirconium hydrogen phosphate with the sulfophenyl or sulfoethyl groups jutting out of the layers into the interlayer space. Ionic conductivity of zirconium 2-sulfoethylphosphonate, titanium and tin 4-sulfophenylphosphonate strongly depends on relative humidity. The charge carriers are protons and their movement is governed by a Grotthuss mechanism.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Solid State Ionics

ISSN

0167-2738

e-ISSN

1872-7689

Svazek periodika

397

Číslo periodika v rámci svazku

September

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

6

Strana od-do

116257

Kód UT WoS článku

000999203000001

EID výsledku v databázi Scopus

2-s2.0-85158063166