Fraser-Suzuki function as an essential tool for mathematical modeling of crystallization in glasses

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F24%3A39920838" target="_blank" >RIV/00216275:25310/24:39920838 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0955221923006763?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0955221923006763?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jeurceramsoc.2023.08.050" target="_blank" >10.1016/j.jeurceramsoc.2023.08.050</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Fraser-Suzuki function as an essential tool for mathematical modeling of crystallization in glasses

Popis výsledku v původním jazyce

The performance of the Fraser-Suzuki function during mathematic deconvolution of crystal growth kinetic processes was extensively analyzed based on theoretical simulations. Regarding pure imitation, the Fraser-Suzuki function well describes processes with moderate negative asymmetry of a3 approximate to&lt;-0.6; -0.2&gt;. Considering the ability of the Fraser-Suzuki function to transfer the kinetic information during the mathematic deconvolution (i. e., performance in the procedure: kinetic signal -&gt; fit by Fraser-Suzuki function -&gt; kinetic analysis of the FraserSuzuki data-curve), it is very well suited for separating processes following single-exponent kinetic models such as the nucleation-growth Johnson-Mehl-Avrami-Kolmogorov model or the nth order reaction model. For the nth order autocatalytic model, the magnitude of errors depends directly on the exponent nNC. Reliable performance of the Fraser-Suzuki function is achieved when resulting nNC falls in &lt;0; 1.2&gt; interval. Combining the FraserSuzuki mathematic deconvolution with the consequent kinetic analysis utilizing the nth order autocatalytic model is highly recommended.

Název v anglickém jazyce

Fraser-Suzuki function as an essential tool for mathematical modeling of crystallization in glasses

Popis výsledku anglicky

The performance of the Fraser-Suzuki function during mathematic deconvolution of crystal growth kinetic processes was extensively analyzed based on theoretical simulations. Regarding pure imitation, the Fraser-Suzuki function well describes processes with moderate negative asymmetry of a3 approximate to&lt;-0.6; -0.2&gt;. Considering the ability of the Fraser-Suzuki function to transfer the kinetic information during the mathematic deconvolution (i. e., performance in the procedure: kinetic signal -&gt; fit by Fraser-Suzuki function -&gt; kinetic analysis of the FraserSuzuki data-curve), it is very well suited for separating processes following single-exponent kinetic models such as the nucleation-growth Johnson-Mehl-Avrami-Kolmogorov model or the nth order reaction model. For the nth order autocatalytic model, the magnitude of errors depends directly on the exponent nNC. Reliable performance of the Fraser-Suzuki function is achieved when resulting nNC falls in &lt;0; 1.2&gt; interval. Combining the FraserSuzuki mathematic deconvolution with the consequent kinetic analysis utilizing the nth order autocatalytic model is highly recommended.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20504 - Ceramics

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of the European Ceramic Society

ISSN

0955-2219

e-ISSN

1873-619X

Svazek periodika

44

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

7

Strana od-do

401-407

Kód UT WoS článku

001092179400001

EID výsledku v databázi Scopus

2-s2.0-85169921219