Solid-state and aggregation-induced emission of novel bicyclic and tricyclic difluoroboron heterocycles

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F24%3A39921765" target="_blank" >RIV/00216275:25310/24:39921765 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.rsc.org/en/content/articlelanding/2024/ma/d4ma00653d" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2024/ma/d4ma00653d</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d4ma00653d" target="_blank" >10.1039/d4ma00653d</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Solid-state and aggregation-induced emission of novel bicyclic and tricyclic difluoroboron heterocycles

Popis výsledku v původním jazyce

Six novel bicyclic and tricyclic difluoroboron NBN and OBN heterocycles were designed here in the quest for novel luminogenic molecular architectures because of their strong application potential as active layers in optoelectronics and as responsive units in sensing. They were prepared and then characterized with spectral (UV-vis, NMR, and luminescence) and electrochemical methods, and assessed via theoretical and X-ray investigations. Most of the compounds are non-emissive in solution, but luminescent in the solid state (red or yellow-green luminescence), and they are AIE active, offering excellent contrast for sensing schemes. Keeping this in view, two compounds were successfully embedded in Pluronic-silica nanoparticles (PluS NPs), coupling the AIEgenic properties of these compounds with the exceptional colloidal stability and functional surface of this type of nanostructure. Here, six novel bicyclic and tricyclic difluoroboron NBN and OBN heterocycles were designed for their strong potential as active layers in optoelectronics and responsive units in sensing applications.

Název v anglickém jazyce

Solid-state and aggregation-induced emission of novel bicyclic and tricyclic difluoroboron heterocycles

Popis výsledku anglicky

Six novel bicyclic and tricyclic difluoroboron NBN and OBN heterocycles were designed here in the quest for novel luminogenic molecular architectures because of their strong application potential as active layers in optoelectronics and as responsive units in sensing. They were prepared and then characterized with spectral (UV-vis, NMR, and luminescence) and electrochemical methods, and assessed via theoretical and X-ray investigations. Most of the compounds are non-emissive in solution, but luminescent in the solid state (red or yellow-green luminescence), and they are AIE active, offering excellent contrast for sensing schemes. Keeping this in view, two compounds were successfully embedded in Pluronic-silica nanoparticles (PluS NPs), coupling the AIEgenic properties of these compounds with the exceptional colloidal stability and functional surface of this type of nanostructure. Here, six novel bicyclic and tricyclic difluoroboron NBN and OBN heterocycles were designed for their strong potential as active layers in optoelectronics and responsive units in sensing applications.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials advances

ISSN

2633-5409

e-ISSN

2633-5409

Svazek periodika

5

Číslo periodika v rámci svazku

19

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

7721-7728

Kód UT WoS článku

001307975000001

EID výsledku v databázi Scopus

2-s2.0-85204901731