Polyacrylate Latex Coating Binders Comprising Polypyrrole Component Prepared with “One-Pot” Synthesis

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F24%3A39922112" target="_blank" >RIV/00216275:25310/24:39922112 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/70883521:28610/24:63582238 RIV/60461373:22810/24:43930188

Výsledek na webu

<a href="https://doi.org/10.3390/coatings14121565" target="_blank" >https://doi.org/10.3390/coatings14121565</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/coatings14121565" target="_blank" >10.3390/coatings14121565</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Polyacrylate Latex Coating Binders Comprising Polypyrrole Component Prepared with “One-Pot” Synthesis

Popis výsledku v původním jazyce

This work deals with the coating properties of synthetic latices comprising two kinds of polymers, specifically polyacrylate and polypyrrole, which were simultaneously formed by semi-continuous emulsion polymerization using a “one-pot” synthesis strategy. In this procedure, both the emulsion polymerization of acrylate monomers and the oxidative polymerization of pyrrole occurred concurrently in one reactor. Polyacrylate latices differing in polypyrrole loading were prepared by applying various dosages of pyrrole, specifically 0, 0.25, and 0.50, based on the fraction of acrylate monomers. The effect of the in situ incorporated polypyrrole component (having the nature of submicron composite polypyrrole-coated polyacrylate latex particles) on the physico-mechanical properties and chemical resistance of the resulting heterogeneous coating films was investigated. The interaction of incorporated polypyrrole and anti-corrosion pigments (see ZnS, Zn3(PO4)2, ZnFe2O4, MoS2, and ZnO) on the corrosion resistance of coatings was evaluated by using the electrochemical linear polarization technique. The polyacrylate latex prepared with the lowest polypyrrole loading (achieved by polymerizing 0.25 wt. % of pyrrole related to acrylic monomers) was found to be the optimum binder for waterborne anticorrosive coatings based on their properties and protective function. Their compatibility with the selected types of pigments was studied for these latex binders. In addition, their influence on the anti-corrosion efficiency of polyacrylate paint films was evaluated using the linear polarization electrochemical technique. For high corrosion resistance, the ZnS and MoS2 pigments, showing compatibility with polyacrylate latices containing the polypyrrole component, proved to be advantageous.

Název v anglickém jazyce

Polyacrylate Latex Coating Binders Comprising Polypyrrole Component Prepared with “One-Pot” Synthesis

Popis výsledku anglicky

This work deals with the coating properties of synthetic latices comprising two kinds of polymers, specifically polyacrylate and polypyrrole, which were simultaneously formed by semi-continuous emulsion polymerization using a “one-pot” synthesis strategy. In this procedure, both the emulsion polymerization of acrylate monomers and the oxidative polymerization of pyrrole occurred concurrently in one reactor. Polyacrylate latices differing in polypyrrole loading were prepared by applying various dosages of pyrrole, specifically 0, 0.25, and 0.50, based on the fraction of acrylate monomers. The effect of the in situ incorporated polypyrrole component (having the nature of submicron composite polypyrrole-coated polyacrylate latex particles) on the physico-mechanical properties and chemical resistance of the resulting heterogeneous coating films was investigated. The interaction of incorporated polypyrrole and anti-corrosion pigments (see ZnS, Zn3(PO4)2, ZnFe2O4, MoS2, and ZnO) on the corrosion resistance of coatings was evaluated by using the electrochemical linear polarization technique. The polyacrylate latex prepared with the lowest polypyrrole loading (achieved by polymerizing 0.25 wt. % of pyrrole related to acrylic monomers) was found to be the optimum binder for waterborne anticorrosive coatings based on their properties and protective function. Their compatibility with the selected types of pigments was studied for these latex binders. In addition, their influence on the anti-corrosion efficiency of polyacrylate paint films was evaluated using the linear polarization electrochemical technique. For high corrosion resistance, the ZnS and MoS2 pigments, showing compatibility with polyacrylate latices containing the polypyrrole component, proved to be advantageous.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20506 - Coating and films

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Coatings

ISSN

2079-6412

e-ISSN

2079-6412

Svazek periodika

14

Číslo periodika v rámci svazku

12

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

24

Strana od-do

1565

Kód UT WoS článku

001383757200001

EID výsledku v databázi Scopus

2-s2.0-85213210573