Small Molecules Effective for Conversion of Lignocellulosic Biomass to Furfural and Its Derivatives

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F24%3A39922157" target="_blank" >RIV/00216275:25310/24:39922157 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.mdpi.com/2073-4344/14/11/791" target="_blank" >https://www.mdpi.com/2073-4344/14/11/791</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal14110791" target="_blank" >10.3390/catal14110791</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Small Molecules Effective for Conversion of Lignocellulosic Biomass to Furfural and Its Derivatives

Popis výsledku v původním jazyce

This review summarizes recent applications of small organic and inorganic molecules as catalysts or solvents (chemical hands and scissors) in the production of furfural (FA), 5-(hydroxymethyl)furfural (HMF), and 5-(chloromethyl)furfural (CMF). The possible transformation of lignocellulosic biomass into a one-pot configuration and two-step technique based on the preliminary separation of hemicellulose, lignin and cellulose with the subsequent hydrolysis of separated polysaccharides is compared and discussed. Interestingly, these rather simple and cheap molecules are catalytically active and enable a high rate of conversion of polysaccharides into furfural and its derivatives. Usually, elevated pressure and reaction temperatures above 150 degrees C are necessary for effective hydrolysis and dehydration of in situ formed monosaccharides; nevertheless, ionic liquids or deep eutectic solvents enable a significant decrease in the reaction temperature and performance of the discussed process at ambient pressure.

Název v anglickém jazyce

Small Molecules Effective for Conversion of Lignocellulosic Biomass to Furfural and Its Derivatives

Popis výsledku anglicky

This review summarizes recent applications of small organic and inorganic molecules as catalysts or solvents (chemical hands and scissors) in the production of furfural (FA), 5-(hydroxymethyl)furfural (HMF), and 5-(chloromethyl)furfural (CMF). The possible transformation of lignocellulosic biomass into a one-pot configuration and two-step technique based on the preliminary separation of hemicellulose, lignin and cellulose with the subsequent hydrolysis of separated polysaccharides is compared and discussed. Interestingly, these rather simple and cheap molecules are catalytically active and enable a high rate of conversion of polysaccharides into furfural and its derivatives. Usually, elevated pressure and reaction temperatures above 150 degrees C are necessary for effective hydrolysis and dehydration of in situ formed monosaccharides; nevertheless, ionic liquids or deep eutectic solvents enable a significant decrease in the reaction temperature and performance of the discussed process at ambient pressure.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

2073-4344

Svazek periodika

14

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

29

Strana od-do

791

Kód UT WoS článku

001364149900001

EID výsledku v databázi Scopus

2-s2.0-85210429285