Production of sulphides in denitrifying woodchip bioreactors

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26110%2F20%3APU136898" target="_blank" >RIV/00216305:26110/20:PU136898 - isvavai.cz</a>

Výsledek na webu

<a href="https://rdcu.be/b5EfC" target="_blank" >https://rdcu.be/b5EfC</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11356-020-10089-4" target="_blank" >10.1007/s11356-020-10089-4</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Production of sulphides in denitrifying woodchip bioreactors

Popis výsledku v původním jazyce

Denitrifying woodchip bioreactors, natural treatment systems used for the reduction of nitrates in agricultural runoff or groundwater, may cause adverse side effects within receiving waters. One of the least studied but nonetheless still serious issues is the production of hydrogen sulphide, which occurs in bioreactors under operating conditions favourable to its creation. The aim of this paper is to elucidate the effect of process parameters on the production of sulphides and the proportion of hydrogen sulphide in a 1-year-long experimental study with four laboratory-scale denitrifying bioreactors. During the study, the strong dependence of sulphate reduction and the production of sulphides on the effluent oxidation-reduction potential (ORP) and nitrate-nitrogen (NO3-N) concentrations of bioreactors became evident. Sulphide formation occurred at concurrent effluent NO3-N concentrations below 3 mg/L and ORPs lower than - 100 mV. The tested hydraulic retention time of 1.7 days was sufficiently long to achieve these conditions. At an effluent pH of 7 or lower, the majority of the total sulphides present were in the form of hydrogen sulphide. It is suggested that in order to avoid the production of hydrogen sulphide, the production of total sulphides has to be minimised.

Název v anglickém jazyce

Production of sulphides in denitrifying woodchip bioreactors

Popis výsledku anglicky

Denitrifying woodchip bioreactors, natural treatment systems used for the reduction of nitrates in agricultural runoff or groundwater, may cause adverse side effects within receiving waters. One of the least studied but nonetheless still serious issues is the production of hydrogen sulphide, which occurs in bioreactors under operating conditions favourable to its creation. The aim of this paper is to elucidate the effect of process parameters on the production of sulphides and the proportion of hydrogen sulphide in a 1-year-long experimental study with four laboratory-scale denitrifying bioreactors. During the study, the strong dependence of sulphate reduction and the production of sulphides on the effluent oxidation-reduction potential (ORP) and nitrate-nitrogen (NO3-N) concentrations of bioreactors became evident. Sulphide formation occurred at concurrent effluent NO3-N concentrations below 3 mg/L and ORPs lower than - 100 mV. The tested hydraulic retention time of 1.7 days was sufficiently long to achieve these conditions. At an effluent pH of 7 or lower, the majority of the total sulphides present were in the form of hydrogen sulphide. It is suggested that in order to avoid the production of hydrogen sulphide, the production of total sulphides has to be minimised.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10511 - Environmental sciences (social aspects to be 5.7)

Projekt

<a href="/cs/project/QJ1520280" target="_blank" >QJ1520280: Udržitelná technologie pro odstranění dusičnanů ze zemědělských smyvů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH

ISSN

0944-1344

e-ISSN

1614-7499

Svazek periodika

27

Číslo periodika v rámci svazku

32

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

8

Strana od-do

40769-40776

Kód UT WoS článku

000548823300008

EID výsledku v databázi Scopus

2-s2.0-85087958063