High entropy alloys (FeCoNi) 0.75 Cr 0.25-x Cu x - thermal stability and physical properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26210%2F24%3APU152256" target="_blank" >RIV/00216305:26210/24:PU152256 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68081723:_____/24:00585635 RIV/00216224:14310/24:00136357

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0925838824012155" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0925838824012155</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jallcom.2024.174628" target="_blank" >10.1016/j.jallcom.2024.174628</a>

Jazyk výsledku

angličtina

Název v původním jazyce

High entropy alloys (FeCoNi) 0.75 Cr 0.25-x Cu x - thermal stability and physical properties

Popis výsledku v původním jazyce

The paper reports on the phase stability of the (FeCoNi) 0.75 Cr 0.25-x Cu x HEA system with equimolar ratio of Fe, Co and Ni by differential scanning calorimetry (DSC) and measurements of physicochemical properties: density, electrical resistivity, Seebeck coefficient, thermal conductivity, and magnetic behaviour in a broad temperature region as well as hardness and elastic modulus at room temperature as a function of the gradual substitution of chromium by copper in a series of (FeCoNi) 0.75 Cr 0.25-x Cu x alloys with different mole fraction of Cu (x = 0, 0.05, 0.1, 0.15 and 0.2). DSC measurements showed that all alloys are thermally stable. Increasing content of Cu was found (i) to increase the formation of a fcc Cu-rich phase, (ii) to strengthen ferromagnetic interactions, resulting in rising ordered magnetic moments, as well as in growing ferromagnetic transition temperatures, and (iii) to distinctly change physical properties like electrical resistivity, thermal expansion, and mechanical properties. Experimental data regarding the phase stability are supported by CALPHAD calculations.

Název v anglickém jazyce

High entropy alloys (FeCoNi) 0.75 Cr 0.25-x Cu x - thermal stability and physical properties

Popis výsledku anglicky

The paper reports on the phase stability of the (FeCoNi) 0.75 Cr 0.25-x Cu x HEA system with equimolar ratio of Fe, Co and Ni by differential scanning calorimetry (DSC) and measurements of physicochemical properties: density, electrical resistivity, Seebeck coefficient, thermal conductivity, and magnetic behaviour in a broad temperature region as well as hardness and elastic modulus at room temperature as a function of the gradual substitution of chromium by copper in a series of (FeCoNi) 0.75 Cr 0.25-x Cu x alloys with different mole fraction of Cu (x = 0, 0.05, 0.1, 0.15 and 0.2). DSC measurements showed that all alloys are thermally stable. Increasing content of Cu was found (i) to increase the formation of a fcc Cu-rich phase, (ii) to strengthen ferromagnetic interactions, resulting in rising ordered magnetic moments, as well as in growing ferromagnetic transition temperatures, and (iii) to distinctly change physical properties like electrical resistivity, thermal expansion, and mechanical properties. Experimental data regarding the phase stability are supported by CALPHAD calculations.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/LM2023039" target="_blank" >LM2023039: Centrum výzkumu a vývoje plazmatu a nanotechnologických povrchových úprav</a><br>

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Alloys and Compounds

ISSN

0925-8388

e-ISSN

1873-4669

Svazek periodika

993

Číslo periodika v rámci svazku

July

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

11

Strana od-do

1-11

Kód UT WoS článku

001238031200001

EID výsledku v databázi Scopus

2-s2.0-85192021062