On the thermal stability and surface and catalytic properties of Cu-Ni nanoparticles

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26210%2F26%3A0199205" target="_blank" >RIV/00216305:26210/26:0199205 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216224:14310/25:00141480

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2468823125003736?pes=vor&utm_source=scopus&getft_integrator=scopus" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2468823125003736?pes=vor&utm_source=scopus&getft_integrator=scopus</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mcat.2025.115188" target="_blank" >10.1016/j.mcat.2025.115188</a>

Jazyk výsledku

angličtina

Název v původním jazyce

On the thermal stability and surface and catalytic properties of Cu-Ni nanoparticles

Popis výsledku v původním jazyce

There is an increased interest in nanoparticle research due to the distinct behaviour of nanoparticles and their compact counterparts with the same chemical composition. The distinct properties include different catalytic activities and phase transformation temperatures. The presented paper deals with the thermal stability and surface and catalytic properties of bimetallic Cu-Ni nanoparticles (NPs). Samples with selected compositions of nanoparticles with a diameter of 8 - 21 nm were prepared via the solvothermal method from copper(II) acetylacetonate and nickel(II) acetylacetonate in an organic solvent mixture of oleylamine and octadec-1-ene. The nanoparticles were characterized by dynamic light scattering (DLS), ultraviolet and visible light spectroscopy (UV-VIS), scanning and transmission electron microscopy (SEM, TEM) equipped with elemental analysis using energy dispersive X-ray spectroscopy (EDX). The elemental composition was characterized by inductively coupled plasma optical emission spectroscopy (ICP-OES). The catalytic properties of the Cu-Ni NPs and the catalytic decomposition of the organic envelope were investigated by Knudsen effusion mass spectrometry (KEMS). Carbon dioxide evolution and creation of decomposition products were observed by mass spectrometry (MS). The optimum efficiency of the catalytic process was observed for Cu-Ni NPs with a copper content of 40-50 %. The thermal stability of the Cu-Ni NPs was monitored using differential scanning calorimetry (DSC) and their melting point depression was evaluated to range from 35.9 to 28.4 degrees C. The results include a description of the processes occurring during the heating of nanoparticles above their melting temperature and during cooling. In addition, new findings were made about the catalytic decomposition of the stabilising organic ligands on the CuNi NPs and the solidus curve of the Cu-Ni phase diagram was determined for Cu-Ni NPs of an average size of 12 nm.

Název v anglickém jazyce

On the thermal stability and surface and catalytic properties of Cu-Ni nanoparticles

Popis výsledku anglicky

There is an increased interest in nanoparticle research due to the distinct behaviour of nanoparticles and their compact counterparts with the same chemical composition. The distinct properties include different catalytic activities and phase transformation temperatures. The presented paper deals with the thermal stability and surface and catalytic properties of bimetallic Cu-Ni nanoparticles (NPs). Samples with selected compositions of nanoparticles with a diameter of 8 - 21 nm were prepared via the solvothermal method from copper(II) acetylacetonate and nickel(II) acetylacetonate in an organic solvent mixture of oleylamine and octadec-1-ene. The nanoparticles were characterized by dynamic light scattering (DLS), ultraviolet and visible light spectroscopy (UV-VIS), scanning and transmission electron microscopy (SEM, TEM) equipped with elemental analysis using energy dispersive X-ray spectroscopy (EDX). The elemental composition was characterized by inductively coupled plasma optical emission spectroscopy (ICP-OES). The catalytic properties of the Cu-Ni NPs and the catalytic decomposition of the organic envelope were investigated by Knudsen effusion mass spectrometry (KEMS). Carbon dioxide evolution and creation of decomposition products were observed by mass spectrometry (MS). The optimum efficiency of the catalytic process was observed for Cu-Ni NPs with a copper content of 40-50 %. The thermal stability of the Cu-Ni NPs was monitored using differential scanning calorimetry (DSC) and their melting point depression was evaluated to range from 35.9 to 28.4 degrees C. The results include a description of the processes occurring during the heating of nanoparticles above their melting temperature and during cooling. In addition, new findings were made about the catalytic decomposition of the stabilising organic ligands on the CuNi NPs and the solidus curve of the Cu-Ni phase diagram was determined for Cu-Ni NPs of an average size of 12 nm.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Molecular Catalysis

ISSN

2468-8231

e-ISSN

—

Svazek periodika

—

Číslo periodika v rámci svazku

582

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

13

Strana od-do

1-13

Kód UT WoS článku

001510356500001

EID výsledku v databázi Scopus

2-s2.0-105004276870