Se-doped Nb2O5-Al2O3 composite-ceramic nanoarrays via the anodizing of Al/Nb bilayer in selenic acid
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26220%2F23%3APU149851" target="_blank" >RIV/00216305:26220/23:PU149851 - isvavai.cz</a>
Výsledek na webu
<a href="https://www.sciencedirect.com/science/article/pii/S0272884223023878" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0272884223023878</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ceramint.2023.08.134" target="_blank" >10.1016/j.ceramint.2023.08.134</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Se-doped Nb2O5-Al2O3 composite-ceramic nanoarrays via the anodizing of Al/Nb bilayer in selenic acid
Popis výsledku v původním jazyce
Novel arrays of Nb2O5-based ceramic nanostructures of various sizes (9-210 nm) and morphologies (dots, goblets, rods) aligned on substrates are fabricated via the anodizing of a thin Nb film through the initially formed porous anodic alumina (PAA) film in 1.5 M selenic acid (H2SeO4) - a new aqueous electrolyte generating extraordinarily thinner PAA pores than any other solutions. Accordingly, the nanostructures formed in the selenic acid are 1.3-fold thinner and better self-ordered than their counterparts formed from the same Al/Nb precursor bilayer in a reference oxalic-acid electrolyte. The nanostructures have a dual (core/shell) composition: the inner material (the core) is stoichiometric Nb2O5, whereas the outer layer (the shell) is a few nm-thick substoichiometric NbOx mixed with Al2O3. The composite-ceramic nanoarrays grow doped with selenium species such as selenate (SeO42-) and selenide (Se-2(-)) anions originating from the electrolyte and migrating inward under the high electric field. The incorporated Se species do not contribute to photoluminescence emission nor hinder the Raman signal from the nanoarrays, which makes them highly promising as Nb2O5-based SERS biosensing substrates. The planar PAA-inbuilt Se-doped Nb2O5-Al2O3 nanostructured ceramic film performs like a high-k low-loss low-leakage-current dielectric promising for on-chip integration. More potential applications of the Se-doped ceramic nanoarrays developed here include biomedical antibacterial coatings, advanced superhydrophobic surfaces, gas-sensing, and catalytic layers.
Název v anglickém jazyce
Se-doped Nb2O5-Al2O3 composite-ceramic nanoarrays via the anodizing of Al/Nb bilayer in selenic acid
Popis výsledku anglicky
Novel arrays of Nb2O5-based ceramic nanostructures of various sizes (9-210 nm) and morphologies (dots, goblets, rods) aligned on substrates are fabricated via the anodizing of a thin Nb film through the initially formed porous anodic alumina (PAA) film in 1.5 M selenic acid (H2SeO4) - a new aqueous electrolyte generating extraordinarily thinner PAA pores than any other solutions. Accordingly, the nanostructures formed in the selenic acid are 1.3-fold thinner and better self-ordered than their counterparts formed from the same Al/Nb precursor bilayer in a reference oxalic-acid electrolyte. The nanostructures have a dual (core/shell) composition: the inner material (the core) is stoichiometric Nb2O5, whereas the outer layer (the shell) is a few nm-thick substoichiometric NbOx mixed with Al2O3. The composite-ceramic nanoarrays grow doped with selenium species such as selenate (SeO42-) and selenide (Se-2(-)) anions originating from the electrolyte and migrating inward under the high electric field. The incorporated Se species do not contribute to photoluminescence emission nor hinder the Raman signal from the nanoarrays, which makes them highly promising as Nb2O5-based SERS biosensing substrates. The planar PAA-inbuilt Se-doped Nb2O5-Al2O3 nanostructured ceramic film performs like a high-k low-loss low-leakage-current dielectric promising for on-chip integration. More potential applications of the Se-doped ceramic nanoarrays developed here include biomedical antibacterial coatings, advanced superhydrophobic surfaces, gas-sensing, and catalytic layers.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20506 - Coating and films
Návaznosti výsledku
Projekt
Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2023
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Ceramics International
ISSN
0272-8842
e-ISSN
1873-3956
Svazek periodika
49
Číslo periodika v rámci svazku
22, Part A
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
14
Strana od-do
34712-34725
Kód UT WoS článku
001096662200001
EID výsledku v databázi Scopus
2-s2.0-85168441018