Destruction of Direct Blue 106 Dye in Underwater Discharge

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F14%3APU88214" target="_blank" >RIV/00216305:26310/14:PU88214 - isvavai.cz</a>

Výsledek na webu

<a href="http://iopscience.iop.org/article/10.1088/1742-6596/516/1/012008" target="_blank" >http://iopscience.iop.org/article/10.1088/1742-6596/516/1/012008</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1088/1742-6596/516/1/012008" target="_blank" >10.1088/1742-6596/516/1/012008</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Destruction of Direct Blue 106 Dye in Underwater Discharge

Popis výsledku v původním jazyce

An application of underwater discharge is one possible way how make the destruction of organic dyes. This contribution presents results of Direct Blue 106 destruction in discharge generated in bubbles. The initial conductivity value of 30 microS/cm was obtained using electrolyte; the starting dye concentration was 20 mg/l. The DC voltage from 1.5 kV to 3.0 kV was applied to generate the discharge at the mean current of 10-30 mA. The system was bubbled through the high voltage capillary electrode by He, Ar and N2 at the constant gas follow of 200 sccm. The dye destruction rate was directly proportional to the applied discharge current, so the highest efficiency was reached at the current of 30 mA. The destruction rate was strongly dependent on the filling gas. While using He and Ar only 4% destruction was obtained during the 20 minutes treatment at 10 mA of discharge current but the decomposition of 52 % was reached if nitrogen was introduced into the high voltage electrode. The destruction efficiency of about 40 % (He, Ar) and over 60 % in nitrogen was reached at discharge current of 30 mA. This enormous difference was probably connected not only to the production of hydrogen peroxide that seems to be usually the main oxidative specie in under water discharges but also atomic and excited nitrogen particles, both atomic and molecular, can have very positive effect in the dye destruction. The detailed study of the kinetic mechanisms leading to the Direct Blue 106 dye destruction will be a subject of the further studies.

Název v anglickém jazyce

Destruction of Direct Blue 106 Dye in Underwater Discharge

Popis výsledku anglicky

An application of underwater discharge is one possible way how make the destruction of organic dyes. This contribution presents results of Direct Blue 106 destruction in discharge generated in bubbles. The initial conductivity value of 30 microS/cm was obtained using electrolyte; the starting dye concentration was 20 mg/l. The DC voltage from 1.5 kV to 3.0 kV was applied to generate the discharge at the mean current of 10-30 mA. The system was bubbled through the high voltage capillary electrode by He, Ar and N2 at the constant gas follow of 200 sccm. The dye destruction rate was directly proportional to the applied discharge current, so the highest efficiency was reached at the current of 30 mA. The destruction rate was strongly dependent on the filling gas. While using He and Ar only 4% destruction was obtained during the 20 minutes treatment at 10 mA of discharge current but the decomposition of 52 % was reached if nitrogen was introduced into the high voltage electrode. The destruction efficiency of about 40 % (He, Ar) and over 60 % in nitrogen was reached at discharge current of 30 mA. This enormous difference was probably connected not only to the production of hydrogen peroxide that seems to be usually the main oxidative specie in under water discharges but also atomic and excited nitrogen particles, both atomic and molecular, can have very positive effect in the dye destruction. The detailed study of the kinetic mechanisms leading to the Direct Blue 106 dye destruction will be a subject of the further studies.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10305 - Fluids and plasma physics (including surface physics)

Projekt

<a href="/cs/project/GD104%2F09%2FH080" target="_blank" >GD104/09/H080: Plazmochemické procesy a jejich technologické aplikace</a><br>

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Physics: Conference Series

ISSN

1742-6588

e-ISSN

1742-6596

Svazek periodika

516

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

4

Strana od-do

012008-012008

Kód UT WoS článku

000344464700008

EID výsledku v databázi Scopus

2-s2.0-84903468093