Hydration of clinkers doped with baryte with and without addition of gypsum

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F19%3APU143386" target="_blank" >RIV/00216305:26310/19:PU143386 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/26232511:_____/19:N0000084

Výsledek na webu

<a href="https://doi.org/10.1007/s10973-019-08632-8" target="_blank" >https://doi.org/10.1007/s10973-019-08632-8</a>

DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Hydration of clinkers doped with baryte with and without addition of gypsum

Popis výsledku v původním jazyce

The use of alternative fuels and raw materials in cement industry leads to the incorporation of some undesirable compounds into the clinker phases. One of them is barium oxide which influences the formation of clinker phases and related properties of the produced cement. Barium in clinker was already studied; the phase composition is changed depending on the amount of barium. However, detailed research focused on hydration properties of these clinkers and cements has not been carried out, yet. A clinker with barium oxide addition to raw meal was prepared. As a source of barium oxide, barium sulphate (baryte) was used in amount of 4% calculated to BaO in the clinker. Barium incorporated in clinker inhibits formation of alite; therefore, lime saturation factor was slightly reduced. Compared to barium carbonate—another source of barium oxide—barium sulphate influences the ratio of clinker phases less significantly. This clinker and a reference sample without barium were milled with and without addition of gypsum. Hydration of barium clinker and cement was examined by XRD in situ hydration and isothermal calorimetry. Hydration products were evaluated by means of thermogravimetric and differential thermal analysis. An increase in total heat of hydration can be seen in samples with barium. The heat is influenced by different hydration of clinker phases with incorporated barium, sulphates and by higher content of free CaO and C3A. According to XRD in situ hydration, hydration of samples with barium is suppressed, the amount of portlandite during the whole measurement is much higher in samples without barium.

Název v anglickém jazyce

Hydration of clinkers doped with baryte with and without addition of gypsum

Popis výsledku anglicky

The use of alternative fuels and raw materials in cement industry leads to the incorporation of some undesirable compounds into the clinker phases. One of them is barium oxide which influences the formation of clinker phases and related properties of the produced cement. Barium in clinker was already studied; the phase composition is changed depending on the amount of barium. However, detailed research focused on hydration properties of these clinkers and cements has not been carried out, yet. A clinker with barium oxide addition to raw meal was prepared. As a source of barium oxide, barium sulphate (baryte) was used in amount of 4% calculated to BaO in the clinker. Barium incorporated in clinker inhibits formation of alite; therefore, lime saturation factor was slightly reduced. Compared to barium carbonate—another source of barium oxide—barium sulphate influences the ratio of clinker phases less significantly. This clinker and a reference sample without barium were milled with and without addition of gypsum. Hydration of barium clinker and cement was examined by XRD in situ hydration and isothermal calorimetry. Hydration products were evaluated by means of thermogravimetric and differential thermal analysis. An increase in total heat of hydration can be seen in samples with barium. The heat is influenced by different hydration of clinker phases with incorporated barium, sulphates and by higher content of free CaO and C3A. According to XRD in situ hydration, hydration of samples with barium is suppressed, the amount of portlandite during the whole measurement is much higher in samples without barium.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/LO1211" target="_blank" >LO1211: Centrum materiálového výzkumu na FCH VUT v Brně - udržitelnost a rozvoj</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Thermal Analysis and Calorimetry

ISSN

1388-6150

e-ISSN

1588-2926

Svazek periodika

138

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

HU - Maďarsko

Počet stran výsledku

8

Strana od-do

1945-1952

Kód UT WoS článku

000494046600011

EID výsledku v databázi Scopus

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