Thermodynamic Analysis of the Landolt-Type Autocatalytic System

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F21%3APU141929" target="_blank" >RIV/00216305:26310/21:PU141929 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.mdpi.com/2073-4344/11/11/1300" target="_blank" >https://www.mdpi.com/2073-4344/11/11/1300</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal11111300" target="_blank" >10.3390/catal11111300</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Thermodynamic Analysis of the Landolt-Type Autocatalytic System

Popis výsledku v původním jazyce

A recent work demonstrated on the example of the Landolt-type reaction system how the simplest autocatalytic loop is described by the kinetic mass action law and proper parametrization of direct and autocatalytic pathways. Using a methodology of non-equilibrium thermodynamics the thermodynamic consistency of that kinetic model is analyzed and the mass action description generalized including an alternative description by the empirical rate equation. Relationships between independent and dependent reactions and their rates are given. The mathematical modeling shows that following the time evolution of reaction rates provides additional insight into autocatalytic behavior. A brief note on thermodynamic driving forces and coupling with diffusion is added. In summary, this work extends and generalizes the kinetic description of the Landolt-type system placing it within the framework of non-equilibrium thermodynamics and demonstrating its thermodynamic consistency.

Název v anglickém jazyce

Thermodynamic Analysis of the Landolt-Type Autocatalytic System

Popis výsledku anglicky

A recent work demonstrated on the example of the Landolt-type reaction system how the simplest autocatalytic loop is described by the kinetic mass action law and proper parametrization of direct and autocatalytic pathways. Using a methodology of non-equilibrium thermodynamics the thermodynamic consistency of that kinetic model is analyzed and the mass action description generalized including an alternative description by the empirical rate equation. Relationships between independent and dependent reactions and their rates are given. The mathematical modeling shows that following the time evolution of reaction rates provides additional insight into autocatalytic behavior. A brief note on thermodynamic driving forces and coupling with diffusion is added. In summary, this work extends and generalizes the kinetic description of the Landolt-type system placing it within the framework of non-equilibrium thermodynamics and demonstrating its thermodynamic consistency.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysts

ISSN

2073-4344

e-ISSN

—

Svazek periodika

11

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

11

Strana od-do

1-11

Kód UT WoS článku

000724437800001

EID výsledku v databázi Scopus

2-s2.0-85117929560