Correlating Hydration of Alkali-Activated Slag Modified by Organic Additives to the Evolution of Its Properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F23%3APU147833" target="_blank" >RIV/00216305:26310/23:PU147833 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.mdpi.com/1996-1944/16/5/1908" target="_blank" >https://www.mdpi.com/1996-1944/16/5/1908</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/ma16051908" target="_blank" >10.3390/ma16051908</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Correlating Hydration of Alkali-Activated Slag Modified by Organic Additives to the Evolution of Its Properties

Popis výsledku v původním jazyce

This study investigates the relationships between the hydration kinetics of waterglass-activated slag and the development of its physical-mechanical properties, as well as its color change. To modify the calorimetric response of alkali-activated slag, hexylene glycol was selected from various alcohols for in-depth experiments. In presence of hexylene glycol, the formation of initial reaction products was restricted to the slag surface, which drastically slowed down the further consumption of dissolved species and slag dissolution and consequently delayed the bulk hydration of the waterglass-activated slag by several days. This allowed to show that the corresponding calorimetric peak is directly related to the rapid evolution of the microstructure and physical-mechanical parameters and to the onset of a blue/green color change recorded as a time-lapse video. Workability loss was correlated with the first half of the second calorimetric peak, while the most rapid increase in strengths and autogenous shrinkage was related to the third calorimetric peak. Ultrasonic pulse velocity increased considerably during both the second and third calorimetric peak. Despite the modified morphology of the initial reaction products, the prolonged induction period, and the slightly reduced degree of hydration induced by hexylene glycol, the overall mechanism of alkaline activation remained unchanged in the long-term perspective. It was hypothesized that the main issue of the use of organic admixtures in alkali-activated systems is the destabilizing effect of these admixtures on soluble silicates introduced into the system with an activator.

Název v anglickém jazyce

Correlating Hydration of Alkali-Activated Slag Modified by Organic Additives to the Evolution of Its Properties

Popis výsledku anglicky

This study investigates the relationships between the hydration kinetics of waterglass-activated slag and the development of its physical-mechanical properties, as well as its color change. To modify the calorimetric response of alkali-activated slag, hexylene glycol was selected from various alcohols for in-depth experiments. In presence of hexylene glycol, the formation of initial reaction products was restricted to the slag surface, which drastically slowed down the further consumption of dissolved species and slag dissolution and consequently delayed the bulk hydration of the waterglass-activated slag by several days. This allowed to show that the corresponding calorimetric peak is directly related to the rapid evolution of the microstructure and physical-mechanical parameters and to the onset of a blue/green color change recorded as a time-lapse video. Workability loss was correlated with the first half of the second calorimetric peak, while the most rapid increase in strengths and autogenous shrinkage was related to the third calorimetric peak. Ultrasonic pulse velocity increased considerably during both the second and third calorimetric peak. Despite the modified morphology of the initial reaction products, the prolonged induction period, and the slightly reduced degree of hydration induced by hexylene glycol, the overall mechanism of alkaline activation remained unchanged in the long-term perspective. It was hypothesized that the main issue of the use of organic admixtures in alkali-activated systems is the destabilizing effect of these admixtures on soluble silicates introduced into the system with an activator.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

<a href="/cs/project/GA20-26896S" target="_blank" >GA20-26896S: Cesta k vývoji organických přísad pro systémy na bázi alkalicky aktivované strusky</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Materials

ISSN

1996-1944

e-ISSN

—

Svazek periodika

16

Číslo periodika v rámci svazku

5

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

18

Strana od-do

1-18

Kód UT WoS článku

000947625200001

EID výsledku v databázi Scopus

—