Structural build-up and breakdown of alkali-activated slag pastes with different order of lignosulfonate and activator addition

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F23%3APU148511" target="_blank" >RIV/00216305:26310/23:PU148511 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0950061823012709" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0950061823012709</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.conbuildmat.2023.131557" target="_blank" >10.1016/j.conbuildmat.2023.131557</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Structural build-up and breakdown of alkali-activated slag pastes with different order of lignosulfonate and activator addition

Popis výsledku v původním jazyce

One of the crucial issues of alkali-activated materials is the application of conventional plasticizers. Lignosulfonate plasticizer (LS) works well for sodium hydroxide-activated slag but loses its efficiency in sodium waterglass-activated slag because of competitive adsorption with silicates. Therefore, the effects of the timing of LS and activator addition on the structural build-up and breakdown of AAS pastes with low-silicate moduli activator (0 to 0.50) were investigated, particularly by means of non-traditional strain sweep tests, which are thoroughly discussed. The rheological tests were correlated with the Vicat needle test and isothermal calorimetry. The results showed the high efficiency of LS in NaOH-activated slag paste over time, regardless of the order of addition of the components of the paste. It was accompanied by a considerable retardation effect of LS on the hydration of AAS. The beneficial effect of LS on the rheological parameters and hydration kinetics decreased rapidly with an increase of the silicate modulus of the activator. The delayed addition of the concentrated silicate-containing activators completely counteracted the slightly beneficial effect of LS and even accelerated the initial structural build-up.

Název v anglickém jazyce

Structural build-up and breakdown of alkali-activated slag pastes with different order of lignosulfonate and activator addition

Popis výsledku anglicky

One of the crucial issues of alkali-activated materials is the application of conventional plasticizers. Lignosulfonate plasticizer (LS) works well for sodium hydroxide-activated slag but loses its efficiency in sodium waterglass-activated slag because of competitive adsorption with silicates. Therefore, the effects of the timing of LS and activator addition on the structural build-up and breakdown of AAS pastes with low-silicate moduli activator (0 to 0.50) were investigated, particularly by means of non-traditional strain sweep tests, which are thoroughly discussed. The rheological tests were correlated with the Vicat needle test and isothermal calorimetry. The results showed the high efficiency of LS in NaOH-activated slag paste over time, regardless of the order of addition of the components of the paste. It was accompanied by a considerable retardation effect of LS on the hydration of AAS. The beneficial effect of LS on the rheological parameters and hydration kinetics decreased rapidly with an increase of the silicate modulus of the activator. The delayed addition of the concentrated silicate-containing activators completely counteracted the slightly beneficial effect of LS and even accelerated the initial structural build-up.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20500 - Materials engineering

Projekt

<a href="/cs/project/GA20-26896S" target="_blank" >GA20-26896S: Cesta k vývoji organických přísad pro systémy na bázi alkalicky aktivované strusky</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Construction and building materials

ISSN

0950-0618

e-ISSN

1879-0526

Svazek periodika

386

Číslo periodika v rámci svazku

červenec

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

12

Strana od-do

„131557“-„“

Kód UT WoS článku

001005413400001

EID výsledku v databázi Scopus

2-s2.0-85156189293