The effect of the combined addition of copper, lithium and sulphur on the formation of Portland cement clinker

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F24%3APU151294" target="_blank" >RIV/00216305:26310/24:PU151294 - isvavai.cz</a>

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/10.1111/jmi.13293" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1111/jmi.13293</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1111/jmi.13293" target="_blank" >10.1111/jmi.13293</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The effect of the combined addition of copper, lithium and sulphur on the formation of Portland cement clinker

Popis výsledku v původním jazyce

Both copper and lithium act as strong fluxes and lower the temperature of the clinker melt formation. Sulphur promotes the stabilisation of more hydraulically active modification of alite M1. It is expected that this combination could produce an alite clinker at significantly lower temperatures with high quality technological parameters. In this paper, the effect of combined oxides of copper, lithium and sulphur addition on the phase composition and clinker structure of Portland cement was investigated. The reference raw meal was prepared from common cement raw materials. Each of the mentioned oxides was added to the reference raw meal in two different concentrations, and 8 combinations were prepared. Chemically pure compounds (NH4)2SO4, CuO and Li2CO3 were used as a source of these oxides. The raw meals were burned to equilibrium at 1450 degrees C. Their phase composition was determined by X-ray diffraction analysis, the microstructure was monitored by optical microscopy, and the microchemistry of the clinker phases was observed by electron microscopy with EDS analysis. It was found that in samples with high lithium or copper content, there is an increase in belite and free lime at the expense of alite. The combination of Cu + Li has the most negative effect, followed by Li alone and Cu alone. The higher SO3 content slightly offsets this negative effect. Clinker is the main intermediate in the production of Portland cement. It is formed at high temperatures in a rotary kiln and its main component is the mineral alite - tricalcium silicate. Alite crystallises in several polymorphic modifications, and sulphur stabilises the modification that increases cement strength. Both copper and lithium act as strong fluxes and lower the temperature of the clinker melt formation. The addition of a combination of these 3 elements to the raw meal for clinker burning is expected to lower the melt formation temperature, and clinker with a high alite content will be formed at lower t

Název v anglickém jazyce

The effect of the combined addition of copper, lithium and sulphur on the formation of Portland cement clinker

Popis výsledku anglicky

Both copper and lithium act as strong fluxes and lower the temperature of the clinker melt formation. Sulphur promotes the stabilisation of more hydraulically active modification of alite M1. It is expected that this combination could produce an alite clinker at significantly lower temperatures with high quality technological parameters. In this paper, the effect of combined oxides of copper, lithium and sulphur addition on the phase composition and clinker structure of Portland cement was investigated. The reference raw meal was prepared from common cement raw materials. Each of the mentioned oxides was added to the reference raw meal in two different concentrations, and 8 combinations were prepared. Chemically pure compounds (NH4)2SO4, CuO and Li2CO3 were used as a source of these oxides. The raw meals were burned to equilibrium at 1450 degrees C. Their phase composition was determined by X-ray diffraction analysis, the microstructure was monitored by optical microscopy, and the microchemistry of the clinker phases was observed by electron microscopy with EDS analysis. It was found that in samples with high lithium or copper content, there is an increase in belite and free lime at the expense of alite. The combination of Cu + Li has the most negative effect, followed by Li alone and Cu alone. The higher SO3 content slightly offsets this negative effect. Clinker is the main intermediate in the production of Portland cement. It is formed at high temperatures in a rotary kiln and its main component is the mineral alite - tricalcium silicate. Alite crystallises in several polymorphic modifications, and sulphur stabilises the modification that increases cement strength. Both copper and lithium act as strong fluxes and lower the temperature of the clinker melt formation. The addition of a combination of these 3 elements to the raw meal for clinker burning is expected to lower the melt formation temperature, and clinker with a high alite content will be formed at lower t

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

21100 - Other engineering and technologies

Projekt

<a href="/cs/project/GA23-05082S" target="_blank" >GA23-05082S: Výzkum kombinovaného účinku oxidů síry, mědi a lithia na tvorbu a vlastnosti slínku portlandského cementu.</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Microscopy

ISSN

0022-2720

e-ISSN

1365-2818

Svazek periodika

294

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

8

Strana od-do

225-232

Kód UT WoS článku

001194227700001

EID výsledku v databázi Scopus

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